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An exploratory study of some liquid catalysts for use with hydrogen peroxide

An exploratory study of some liquid catalysts for use with hydrogen peroxide
An exploratory study of some liquid catalysts for use with hydrogen peroxide
Liquid catalysts for decomposing hydrogen peroxide in rocket engines have certain advantages over solid catalysts. However, some liquid catalysts have a tendency to precipitate at the outlet to the injector, which militates against their use for multiple engine restarts. In the study reported here, experiments have been carried out with several liquid catalysts, from which the rate of reaction and the tendency to form precipitates are compared against the benchmark catalytic agent, sodium permanganate. The results to date suggest that, although exhibiting a reduced tendency to form precipitates, none of the candidate agents considered match the reaction rate of sodium permanganate. However, at least one of the agents (sodium iodide) was found to initiate a very high decomposition rate, albeit with an undesirable initial delay. It was found that ferrous chloride tetrahydrate had no such delay and was capable of producing useful decomposition temperatures.
hydrogen peroxide, liquid catalysts, rocket
Musker, A.J.
2458b670-f376-434a-89b3-1202378170a9
Roberts, G.T.
deaf59ac-e4ee-4fc2-accf-df0639d39368
Musker, A.J.
2458b670-f376-434a-89b3-1202378170a9
Roberts, G.T.
deaf59ac-e4ee-4fc2-accf-df0639d39368

Musker, A.J. and Roberts, G.T. (2006) An exploratory study of some liquid catalysts for use with hydrogen peroxide. 3rd International Conference on Green Propellants, Poitiers, France. 16 - 19 Sep 2006. (Submitted)

Record type: Conference or Workshop Item (Paper)

Abstract

Liquid catalysts for decomposing hydrogen peroxide in rocket engines have certain advantages over solid catalysts. However, some liquid catalysts have a tendency to precipitate at the outlet to the injector, which militates against their use for multiple engine restarts. In the study reported here, experiments have been carried out with several liquid catalysts, from which the rate of reaction and the tendency to form precipitates are compared against the benchmark catalytic agent, sodium permanganate. The results to date suggest that, although exhibiting a reduced tendency to form precipitates, none of the candidate agents considered match the reaction rate of sodium permanganate. However, at least one of the agents (sodium iodide) was found to initiate a very high decomposition rate, albeit with an undesirable initial delay. It was found that ferrous chloride tetrahydrate had no such delay and was capable of producing useful decomposition temperatures.

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More information

Submitted date: August 2006
Venue - Dates: 3rd International Conference on Green Propellants, Poitiers, France, 2006-09-16 - 2006-09-19
Keywords: hydrogen peroxide, liquid catalysts, rocket
Organisations: Aerodynamics & Flight Mechanics

Identifiers

Local EPrints ID: 43657
URI: http://eprints.soton.ac.uk/id/eprint/43657
PURE UUID: c102ca94-0a48-474f-963b-ddcd453eca9e

Catalogue record

Date deposited: 25 Jan 2007
Last modified: 11 Dec 2021 16:17

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Contributors

Author: A.J. Musker
Author: G.T. Roberts

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