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Voltammetric reduction and re-oxidation of solid coordination polymers of dihydroxybenzoquinone

Voltammetric reduction and re-oxidation of solid coordination polymers of dihydroxybenzoquinone
Voltammetric reduction and re-oxidation of solid coordination polymers of dihydroxybenzoquinone

Crystalline (PMePh 3) 2[Cd 2(dhbq) 3], (dhbq 2- = deprotonated 2,5-dihydroxybenzoquinone, H 2dhbq), attached to electrode surfaces, survives repeated cycles of reduction followed by re-oxidation when placed in contact with aqueous electrolyte media. The results afford encouragement that a range of coordination networks containing redox active connecting ligands and/or redox active metal centres may be reducible or oxidisable in the solid state.

1359-7345
11422-11424
Abrahams, Brendan F.
9d8972b1-63c7-4ee8-b5b6-5ccfbcf3f798
Bond, Alan M.
be9f2fbd-5ee2-4f0b-ab71-9b12263ad01d
Le, Thanh Hai
af2181e6-ade9-4740-a65c-ca47424255f0
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Nafady, Ayman
058288c7-ea28-4acc-a894-7d11f0444ee6
Robson, Richard
2c74c03e-58f1-4fc3-9b11-ff00e28d09c8
Vo, Nguyen
f01d90e6-58ec-4172-82c5-663946211969
Abrahams, Brendan F.
9d8972b1-63c7-4ee8-b5b6-5ccfbcf3f798
Bond, Alan M.
be9f2fbd-5ee2-4f0b-ab71-9b12263ad01d
Le, Thanh Hai
af2181e6-ade9-4740-a65c-ca47424255f0
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Nafady, Ayman
058288c7-ea28-4acc-a894-7d11f0444ee6
Robson, Richard
2c74c03e-58f1-4fc3-9b11-ff00e28d09c8
Vo, Nguyen
f01d90e6-58ec-4172-82c5-663946211969

Abrahams, Brendan F., Bond, Alan M., Le, Thanh Hai, McCormick, Laura J., Nafady, Ayman, Robson, Richard and Vo, Nguyen (2012) Voltammetric reduction and re-oxidation of solid coordination polymers of dihydroxybenzoquinone. Chemical Communications, 48 (93), 11422-11424. (doi:10.1039/c2cc34687g).

Record type: Article

Abstract

Crystalline (PMePh 3) 2[Cd 2(dhbq) 3], (dhbq 2- = deprotonated 2,5-dihydroxybenzoquinone, H 2dhbq), attached to electrode surfaces, survives repeated cycles of reduction followed by re-oxidation when placed in contact with aqueous electrolyte media. The results afford encouragement that a range of coordination networks containing redox active connecting ligands and/or redox active metal centres may be reducible or oxidisable in the solid state.

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More information

Accepted/In Press date: 5 October 2012
e-pub ahead of print date: 23 October 2012
Published date: 4 December 2012

Identifiers

Local EPrints ID: 437890
URI: http://eprints.soton.ac.uk/id/eprint/437890
ISSN: 1359-7345
PURE UUID: dc6d0244-efa3-4fef-8539-0b88716c3b11
ORCID for Laura J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717

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Date deposited: 21 Feb 2020 17:31
Last modified: 07 Oct 2020 02:27

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Contributors

Author: Brendan F. Abrahams
Author: Alan M. Bond
Author: Thanh Hai Le
Author: Ayman Nafady
Author: Richard Robson
Author: Nguyen Vo

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