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Coordination polymers of 5-alkoxy isophthalic acids

Coordination polymers of 5-alkoxy isophthalic acids
Coordination polymers of 5-alkoxy isophthalic acids

The topology of coordination polymers containing 5-alkoxy isophthalic acids and first row transition metals was found to be dependent on the combination of solvent system used and length of the alkyl chain. Four different framework types were identified: Phase A, M6(ROip)5(OH)2(H2O)4·xH2O (M = Co and R = Et, Pr, or nBu, or M = Zn and R = Et); Phase B, M2(ROip)2(H2O) (M = Co or Zn and R = Et, Pr, nBu, or iBu, or M = Mn and R = nBu or iBu); Phase C, Zn3(EtOip)2(OH)2; and Phase D, Zn2(EtOip)2(H2O)3. Preliminary screening of the NO storage and release capabilities of the Co-containing materials is also reported.

1528-7483
5771-5780
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Morris, Samuel A.
e1cae713-3787-412d-b7d0-02ad52eebb04
Slawin, Alexandra M.Z.
015022ad-00f0-4639-9b31-14b1bd0c234d
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
Morris, Russell E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Morris, Samuel A.
e1cae713-3787-412d-b7d0-02ad52eebb04
Slawin, Alexandra M.Z.
015022ad-00f0-4639-9b31-14b1bd0c234d
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
Morris, Russell E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c

McCormick, Laura J., Morris, Samuel A., Slawin, Alexandra M.Z., Teat, Simon J. and Morris, Russell E. (2016) Coordination polymers of 5-alkoxy isophthalic acids. Crystal Growth and Design, 16 (10), 5771-5780. (doi:10.1021/acs.cgd.6b00853).

Record type: Article

Abstract

The topology of coordination polymers containing 5-alkoxy isophthalic acids and first row transition metals was found to be dependent on the combination of solvent system used and length of the alkyl chain. Four different framework types were identified: Phase A, M6(ROip)5(OH)2(H2O)4·xH2O (M = Co and R = Et, Pr, or nBu, or M = Zn and R = Et); Phase B, M2(ROip)2(H2O) (M = Co or Zn and R = Et, Pr, nBu, or iBu, or M = Mn and R = nBu or iBu); Phase C, Zn3(EtOip)2(OH)2; and Phase D, Zn2(EtOip)2(H2O)3. Preliminary screening of the NO storage and release capabilities of the Co-containing materials is also reported.

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e-pub ahead of print date: 7 September 2016
Published date: 5 October 2016

Identifiers

Local EPrints ID: 437900
URI: http://eprints.soton.ac.uk/id/eprint/437900
ISSN: 1528-7483
PURE UUID: ef0f434f-3a46-4493-8302-160b104b8ba1
ORCID for Laura J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717

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Date deposited: 24 Feb 2020 17:30
Last modified: 07 Oct 2020 02:27

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Contributors

Author: Samuel A. Morris
Author: Alexandra M.Z. Slawin
Author: Simon J. Teat
Author: Russell E. Morris

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