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Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8
Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

1463-9076
23908-23914
Magdysyuk, O. V.
65a458c7-9520-41ba-a317-b2714f6aad37
Adams, F.
be10d9d3-a8bb-4e46-82cd-ddb3c7f57f43
Liermann, H. P.
061a0002-52f6-4049-8029-2cdc98594e9f
Spanopoulos, I.
2a0e1e49-7ad4-417e-b6c5-dd7816fe6e3e
Trikalitis, P. N.
8da30d5d-917b-416d-a9e6-635325a8fe5f
Hirscher, M.
77225eec-b2ba-4e51-aad7-d6a3700aa418
Morris, R. E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c
Duncan, M. J.
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McCormick, L. J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Dinnebier, R. E.
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Magdysyuk, O. V.
65a458c7-9520-41ba-a317-b2714f6aad37
Adams, F.
be10d9d3-a8bb-4e46-82cd-ddb3c7f57f43
Liermann, H. P.
061a0002-52f6-4049-8029-2cdc98594e9f
Spanopoulos, I.
2a0e1e49-7ad4-417e-b6c5-dd7816fe6e3e
Trikalitis, P. N.
8da30d5d-917b-416d-a9e6-635325a8fe5f
Hirscher, M.
77225eec-b2ba-4e51-aad7-d6a3700aa418
Morris, R. E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c
Duncan, M. J.
928ee263-5675-49f8-91c8-195452126c28
McCormick, L. J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Dinnebier, R. E.
452918d4-f973-4d6f-aed4-3ac908e11413

Magdysyuk, O. V., Adams, F., Liermann, H. P., Spanopoulos, I., Trikalitis, P. N., Hirscher, M., Morris, R. E., Duncan, M. J., McCormick, L. J. and Dinnebier, R. E. (2014) Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8. Physical Chemistry Chemical Physics, 16 (43), 23908-23914. (doi:10.1039/c4cp03298e).

Record type: Article

Abstract

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

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More information

Accepted/In Press date: 16 September 2014
e-pub ahead of print date: 17 September 2014
Published date: 15 October 2014

Identifiers

Local EPrints ID: 438032
URI: http://eprints.soton.ac.uk/id/eprint/438032
ISSN: 1463-9076
PURE UUID: d6015591-ad58-429f-8d9d-d2eef546c5b2
ORCID for L. J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717

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Date deposited: 26 Feb 2020 17:31
Last modified: 06 Jun 2024 02:08

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Contributors

Author: O. V. Magdysyuk
Author: F. Adams
Author: H. P. Liermann
Author: I. Spanopoulos
Author: P. N. Trikalitis
Author: M. Hirscher
Author: R. E. Morris
Author: M. J. Duncan
Author: L. J. McCormick ORCID iD
Author: R. E. Dinnebier

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