The University of Southampton
University of Southampton Institutional Repository
Warning ePrints Soton is experiencing an issue with some file downloads not being available. We are working hard to fix this. Please bear with us.

A robust and unique iron(ii) mosaic-like MOF

A robust and unique iron(ii) mosaic-like MOF
A robust and unique iron(ii) mosaic-like MOF
A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(II), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(II)–F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.
1359-7345
5526-5529
Fernandez-Bartolome, Estefania
9e11dd3b-217f-4bc5-a964-1081cbe3c63d
Santos, Jose
099caf8f-657e-437e-b1e2-8a562ca2f329
Khodabakhshi, Saeed
ca44317e-7079-4c8f-8a41-4b9c77bb34d8
McCormick McPherson, Laura
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
Saenz de Pipaon, Cristina
f1e9805d-51f1-4d08-ace0-ddc303fa346a
Galán-Mascarós, José R.
816f8030-d13a-4235-b2e6-90b0313abf2e
Martín, Nazario
78784ddd-8eb2-421f-84c2-baed719acbf2
Costa, José Sánchez
2002b5ee-32c7-4d15-987d-a63c9b7bca52
Fernandez-Bartolome, Estefania
9e11dd3b-217f-4bc5-a964-1081cbe3c63d
Santos, Jose
099caf8f-657e-437e-b1e2-8a562ca2f329
Khodabakhshi, Saeed
ca44317e-7079-4c8f-8a41-4b9c77bb34d8
McCormick McPherson, Laura
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
Saenz de Pipaon, Cristina
f1e9805d-51f1-4d08-ace0-ddc303fa346a
Galán-Mascarós, José R.
816f8030-d13a-4235-b2e6-90b0313abf2e
Martín, Nazario
78784ddd-8eb2-421f-84c2-baed719acbf2
Costa, José Sánchez
2002b5ee-32c7-4d15-987d-a63c9b7bca52

Fernandez-Bartolome, Estefania, Santos, Jose, Khodabakhshi, Saeed, McCormick McPherson, Laura, Teat, Simon J., Saenz de Pipaon, Cristina, Galán-Mascarós, José R., Martín, Nazario and Costa, José Sánchez (2018) A robust and unique iron(ii) mosaic-like MOF. Chemical Communications, 54 (44), 5526-5529. (doi:10.1039/C8CC01561A).

Record type: Article

Abstract

A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(II), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(II)–F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.

This record has no associated files available for download.

More information

Accepted/In Press date: 30 April 2018
e-pub ahead of print date: 30 April 2018
Published date: 4 June 2018

Identifiers

Local EPrints ID: 438276
URI: http://eprints.soton.ac.uk/id/eprint/438276
ISSN: 1359-7345
PURE UUID: 6ee2898f-1d53-4898-a057-16c1067c0079
ORCID for Laura McCormick McPherson: ORCID iD orcid.org/0000-0002-6634-4717

Catalogue record

Date deposited: 04 Mar 2020 17:32
Last modified: 07 Oct 2020 02:27

Export record

Altmetrics

Contributors

Author: Estefania Fernandez-Bartolome
Author: Jose Santos
Author: Saeed Khodabakhshi
Author: Simon J. Teat
Author: Cristina Saenz de Pipaon
Author: José R. Galán-Mascarós
Author: Nazario Martín
Author: José Sánchez Costa

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×