A robust and unique iron(ii) mosaic-like MOF
A robust and unique iron(ii) mosaic-like MOF
A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(II), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(II)–F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.
5526-5529
Fernandez-Bartolome, Estefania
9e11dd3b-217f-4bc5-a964-1081cbe3c63d
Santos, Jose
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Khodabakhshi, Saeed
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McCormick McPherson, Laura
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Teat, Simon J.
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Saenz de Pipaon, Cristina
f1e9805d-51f1-4d08-ace0-ddc303fa346a
Galán-Mascarós, José R.
816f8030-d13a-4235-b2e6-90b0313abf2e
Martín, Nazario
78784ddd-8eb2-421f-84c2-baed719acbf2
Costa, José Sánchez
2002b5ee-32c7-4d15-987d-a63c9b7bca52
4 June 2018
Fernandez-Bartolome, Estefania
9e11dd3b-217f-4bc5-a964-1081cbe3c63d
Santos, Jose
099caf8f-657e-437e-b1e2-8a562ca2f329
Khodabakhshi, Saeed
ca44317e-7079-4c8f-8a41-4b9c77bb34d8
McCormick McPherson, Laura
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
Saenz de Pipaon, Cristina
f1e9805d-51f1-4d08-ace0-ddc303fa346a
Galán-Mascarós, José R.
816f8030-d13a-4235-b2e6-90b0313abf2e
Martín, Nazario
78784ddd-8eb2-421f-84c2-baed719acbf2
Costa, José Sánchez
2002b5ee-32c7-4d15-987d-a63c9b7bca52
Fernandez-Bartolome, Estefania, Santos, Jose, Khodabakhshi, Saeed, McCormick McPherson, Laura, Teat, Simon J., Saenz de Pipaon, Cristina, Galán-Mascarós, José R., Martín, Nazario and Costa, José Sánchez
(2018)
A robust and unique iron(ii) mosaic-like MOF.
Chemical Communications, 54 (44), .
(doi:10.1039/C8CC01561A).
Abstract
A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(II), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(II)–F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.
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Accepted/In Press date: 30 April 2018
e-pub ahead of print date: 30 April 2018
Published date: 4 June 2018
Identifiers
Local EPrints ID: 438276
URI: http://eprints.soton.ac.uk/id/eprint/438276
ISSN: 1359-7345
PURE UUID: 6ee2898f-1d53-4898-a057-16c1067c0079
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Date deposited: 04 Mar 2020 17:32
Last modified: 17 Mar 2024 04:01
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Contributors
Author:
Estefania Fernandez-Bartolome
Author:
Jose Santos
Author:
Saeed Khodabakhshi
Author:
Simon J. Teat
Author:
Cristina Saenz de Pipaon
Author:
José R. Galán-Mascarós
Author:
Nazario Martín
Author:
José Sánchez Costa
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