The University of Southampton
University of Southampton Institutional Repository

'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst

'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst
'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst
The ‘pincer’ pyridine-dicarbene and bipyridyl-carbene ruthenium benzylidene complexes, Ru(C–N–C)Cl2(@CHPh) and Ru(C–N– N)Cl2(@CHPh), (C–N–C) = 2,6-bis(DiPP-imidazol-2-ylidene)pyridine, (C–N–N) = (DiPP-imidazol-2-ylidene)bipyridine, have been prepared and characterised by spectroscopic and diffraction methods. They exhibit moderate metathesis activity. Non-symmetrical linear tridentate ether-functionalised N-heterocyclic carbene pro-ligands are also described.
0022-328X
5204-5210
Wright, Joseph A.
3e730775-dda4-4d1e-83ad-8b1e96fb2cbe
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Motherwell, William B.
77559985-75b3-4d25-9a26-9a93c520a871
Carroll, Robert J.
2ea630ba-95a1-48ce-a03a-bba5ab4e7f3a
Ellwood, Simon
b78c870e-bc33-4c96-898b-cc273bd6ecc5
Wright, Joseph A.
3e730775-dda4-4d1e-83ad-8b1e96fb2cbe
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Motherwell, William B.
77559985-75b3-4d25-9a26-9a93c520a871
Carroll, Robert J.
2ea630ba-95a1-48ce-a03a-bba5ab4e7f3a
Ellwood, Simon
b78c870e-bc33-4c96-898b-cc273bd6ecc5

Wright, Joseph A., Danopoulos, Andreas A., Motherwell, William B., Carroll, Robert J. and Ellwood, Simon (2006) 'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst. Journal of Organometallic Chemistry, 691 (24-25), 5204-5210. (doi:10.1016/j.jorganchem.2006.08.023).

Record type: Article

Abstract

The ‘pincer’ pyridine-dicarbene and bipyridyl-carbene ruthenium benzylidene complexes, Ru(C–N–C)Cl2(@CHPh) and Ru(C–N– N)Cl2(@CHPh), (C–N–C) = 2,6-bis(DiPP-imidazol-2-ylidene)pyridine, (C–N–N) = (DiPP-imidazol-2-ylidene)bipyridine, have been prepared and characterised by spectroscopic and diffraction methods. They exhibit moderate metathesis activity. Non-symmetrical linear tridentate ether-functionalised N-heterocyclic carbene pro-ligands are also described.

This record has no associated files available for download.

More information

Published date: 2006

Identifiers

Local EPrints ID: 43829
URI: http://eprints.soton.ac.uk/id/eprint/43829
ISSN: 0022-328X
PURE UUID: e550b856-4ed6-4092-a626-a328f7752df2

Catalogue record

Date deposited: 31 Jan 2007
Last modified: 15 Mar 2024 08:58

Export record

Altmetrics

Contributors

Author: Joseph A. Wright
Author: Andreas A. Danopoulos
Author: William B. Motherwell
Author: Robert J. Carroll
Author: Simon Ellwood

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×