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'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst

'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst
'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst
The ‘pincer’ pyridine-dicarbene and bipyridyl-carbene ruthenium benzylidene complexes, Ru(C–N–C)Cl2(@CHPh) and Ru(C–N– N)Cl2(@CHPh), (C–N–C) = 2,6-bis(DiPP-imidazol-2-ylidene)pyridine, (C–N–N) = (DiPP-imidazol-2-ylidene)bipyridine, have been prepared and characterised by spectroscopic and diffraction methods. They exhibit moderate metathesis activity. Non-symmetrical linear tridentate ether-functionalised N-heterocyclic carbene pro-ligands are also described.
0022-328X
5204-5210
Wright, Joseph A.
3e730775-dda4-4d1e-83ad-8b1e96fb2cbe
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Motherwell, William B.
77559985-75b3-4d25-9a26-9a93c520a871
Carroll, Robert J.
2ea630ba-95a1-48ce-a03a-bba5ab4e7f3a
Ellwood, Simon
b78c870e-bc33-4c96-898b-cc273bd6ecc5
Wright, Joseph A.
3e730775-dda4-4d1e-83ad-8b1e96fb2cbe
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Motherwell, William B.
77559985-75b3-4d25-9a26-9a93c520a871
Carroll, Robert J.
2ea630ba-95a1-48ce-a03a-bba5ab4e7f3a
Ellwood, Simon
b78c870e-bc33-4c96-898b-cc273bd6ecc5

Wright, Joseph A., Danopoulos, Andreas A., Motherwell, William B., Carroll, Robert J. and Ellwood, Simon (2006) 'Pincer’ pyridyl- and bipyridyl-N-heterocyclic carbene analogues of the Grubbs’ metathesis catalyst. Journal of Organometallic Chemistry, 691 (24-25), 5204-5210. (doi:10.1016/j.jorganchem.2006.08.023).

Record type: Article

Abstract

The ‘pincer’ pyridine-dicarbene and bipyridyl-carbene ruthenium benzylidene complexes, Ru(C–N–C)Cl2(@CHPh) and Ru(C–N– N)Cl2(@CHPh), (C–N–C) = 2,6-bis(DiPP-imidazol-2-ylidene)pyridine, (C–N–N) = (DiPP-imidazol-2-ylidene)bipyridine, have been prepared and characterised by spectroscopic and diffraction methods. They exhibit moderate metathesis activity. Non-symmetrical linear tridentate ether-functionalised N-heterocyclic carbene pro-ligands are also described.

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Published date: 2006

Identifiers

Local EPrints ID: 43829
URI: http://eprints.soton.ac.uk/id/eprint/43829
ISSN: 0022-328X
PURE UUID: e550b856-4ed6-4092-a626-a328f7752df2

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Date deposited: 31 Jan 2007
Last modified: 13 Mar 2019 21:08

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