Tuning the nitric oxide release behavior of amino functionalized HKUST-1
Tuning the nitric oxide release behavior of amino functionalized HKUST-1
Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R = Me, Et, nPr, and iPr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.
Amino functionalized HKUST-1, HKUST-1, Metal-organic framework, Nitric oxide release, NONOate
118-126
Peikert, Katharina
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McCormick, Laura J.
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Cattaneo, Damiano
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Duncan, Morven J.
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Hoffmann, Frank
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Khan, Arafat H.
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Bertmer, Marko
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Morris, Russell E.
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Fröba, Michael
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1 November 2015
Peikert, Katharina
dacc22be-29aa-4233-b760-01b903a30ee6
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Cattaneo, Damiano
120199e7-ae35-4613-a761-885bdd459fef
Duncan, Morven J.
3a058226-93c6-4521-824c-53608a7d5e0c
Hoffmann, Frank
971514f4-1e98-4670-882f-1bb4230568cf
Khan, Arafat H.
6e19f396-fb88-4b5f-8c61-6297a5e23d5f
Bertmer, Marko
f6c8a9bf-8873-4557-9fe3-adbde4fd9d4c
Morris, Russell E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c
Fröba, Michael
7d8516f0-49ca-40af-b6d4-5caf9bd18893
Peikert, Katharina, McCormick, Laura J., Cattaneo, Damiano, Duncan, Morven J., Hoffmann, Frank, Khan, Arafat H., Bertmer, Marko, Morris, Russell E. and Fröba, Michael
(2015)
Tuning the nitric oxide release behavior of amino functionalized HKUST-1.
Microporous and Mesoporous Materials, 216, .
(doi:10.1016/j.micromeso.2015.06.020).
Abstract
Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R = Me, Et, nPr, and iPr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.
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Accepted/In Press date: 15 June 2015
e-pub ahead of print date: 25 June 2015
Published date: 1 November 2015
Keywords:
Amino functionalized HKUST-1, HKUST-1, Metal-organic framework, Nitric oxide release, NONOate
Identifiers
Local EPrints ID: 438797
URI: http://eprints.soton.ac.uk/id/eprint/438797
ISSN: 1387-1811
PURE UUID: dccc728c-777b-48ac-be1b-64d73b4f0c05
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Date deposited: 24 Mar 2020 17:52
Last modified: 06 Jun 2024 02:08
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Contributors
Author:
Katharina Peikert
Author:
Damiano Cattaneo
Author:
Morven J. Duncan
Author:
Frank Hoffmann
Author:
Arafat H. Khan
Author:
Marko Bertmer
Author:
Russell E. Morris
Author:
Michael Fröba
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