The University of Southampton
University of Southampton Institutional Repository
Warning ePrints Soton is experiencing an issue with some file downloads not being available. We are working hard to fix this. Please bear with us.

Tuning the nitric oxide release behavior of amino functionalized HKUST-1

Tuning the nitric oxide release behavior of amino functionalized HKUST-1
Tuning the nitric oxide release behavior of amino functionalized HKUST-1

Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R = Me, Et, nPr, and iPr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.

Amino functionalized HKUST-1, HKUST-1, Metal-organic framework, Nitric oxide release, NONOate
1387-1811
118-126
Peikert, Katharina
dacc22be-29aa-4233-b760-01b903a30ee6
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Cattaneo, Damiano
120199e7-ae35-4613-a761-885bdd459fef
Duncan, Morven J.
3a058226-93c6-4521-824c-53608a7d5e0c
Hoffmann, Frank
971514f4-1e98-4670-882f-1bb4230568cf
Khan, Arafat H.
6e19f396-fb88-4b5f-8c61-6297a5e23d5f
Bertmer, Marko
f6c8a9bf-8873-4557-9fe3-adbde4fd9d4c
Morris, Russell E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c
Fröba, Michael
7d8516f0-49ca-40af-b6d4-5caf9bd18893
Peikert, Katharina
dacc22be-29aa-4233-b760-01b903a30ee6
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Cattaneo, Damiano
120199e7-ae35-4613-a761-885bdd459fef
Duncan, Morven J.
3a058226-93c6-4521-824c-53608a7d5e0c
Hoffmann, Frank
971514f4-1e98-4670-882f-1bb4230568cf
Khan, Arafat H.
6e19f396-fb88-4b5f-8c61-6297a5e23d5f
Bertmer, Marko
f6c8a9bf-8873-4557-9fe3-adbde4fd9d4c
Morris, Russell E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c
Fröba, Michael
7d8516f0-49ca-40af-b6d4-5caf9bd18893

Peikert, Katharina, McCormick, Laura J., Cattaneo, Damiano, Duncan, Morven J., Hoffmann, Frank, Khan, Arafat H., Bertmer, Marko, Morris, Russell E. and Fröba, Michael (2015) Tuning the nitric oxide release behavior of amino functionalized HKUST-1. Microporous and Mesoporous Materials, 216, 118-126. (doi:10.1016/j.micromeso.2015.06.020).

Record type: Article

Abstract

Four new secondary amino functionalized trimesic acid ligands (H3RNHbtc, R = Me, Et, nPr, and iPr) were synthesized. When used in combination with H3btc these ligands lead to four new mixed-linker metal-organic frameworks (MOFs) which we call UHM-36, UHM-37, UHM-38, and UHM-39. All MOFs are isostructural to HKUST-1. We tested these MOFs as nitric oxide storage and release materials and investigate the influence of the amine groups on the NO storage capacity of the MOFs. The results were compared to the unfunctionalized HKUST-1, i.e. Cu3(btc)2.

This record has no associated files available for download.

More information

Accepted/In Press date: 15 June 2015
e-pub ahead of print date: 25 June 2015
Published date: 1 November 2015
Keywords: Amino functionalized HKUST-1, HKUST-1, Metal-organic framework, Nitric oxide release, NONOate

Identifiers

Local EPrints ID: 438797
URI: http://eprints.soton.ac.uk/id/eprint/438797
ISSN: 1387-1811
PURE UUID: dccc728c-777b-48ac-be1b-64d73b4f0c05
ORCID for Laura J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717

Catalogue record

Date deposited: 24 Mar 2020 17:52
Last modified: 26 Nov 2021 03:21

Export record

Altmetrics

Contributors

Author: Katharina Peikert
Author: Damiano Cattaneo
Author: Morven J. Duncan
Author: Frank Hoffmann
Author: Arafat H. Khan
Author: Marko Bertmer
Author: Russell E. Morris
Author: Michael Fröba

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×