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Coordination polymers of ZnII and 5-methoxy isophthalate

Coordination polymers of ZnII and 5-methoxy isophthalate
Coordination polymers of ZnII and 5-methoxy isophthalate

Solvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.

1477-9226
17686-17695
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Morris, Samuel A.
e1cae713-3787-412d-b7d0-02ad52eebb04
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
McPherson, Matthew J.
d3c78165-4cd3-4607-bdb4-465ce844bc96
Slawin, Alexandra M.Z.
015022ad-00f0-4639-9b31-14b1bd0c234d
Morris, Russell E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Morris, Samuel A.
e1cae713-3787-412d-b7d0-02ad52eebb04
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
McPherson, Matthew J.
d3c78165-4cd3-4607-bdb4-465ce844bc96
Slawin, Alexandra M.Z.
015022ad-00f0-4639-9b31-14b1bd0c234d
Morris, Russell E.
0c724305-d30c-4be8-8b1f-bec10ca5f91c

McCormick, Laura J., Morris, Samuel A., Teat, Simon J., McPherson, Matthew J., Slawin, Alexandra M.Z. and Morris, Russell E. (2015) Coordination polymers of ZnII and 5-methoxy isophthalate. Dalton Transactions, 44 (40), 17686-17695. (doi:10.1039/c5dt02924d).

Record type: Article

Abstract

Solvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.

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More information

Accepted/In Press date: 15 September 2015
e-pub ahead of print date: 21 September 2015
Published date: 28 October 2015

Identifiers

Local EPrints ID: 438860
URI: http://eprints.soton.ac.uk/id/eprint/438860
ISSN: 1477-9226
PURE UUID: bc327179-26cf-4f67-a2ec-279ebd793ca1
ORCID for Laura J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717

Catalogue record

Date deposited: 25 Mar 2020 17:32
Last modified: 07 Oct 2020 02:27

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Contributors

Author: Samuel A. Morris
Author: Simon J. Teat
Author: Matthew J. McPherson
Author: Alexandra M.Z. Slawin
Author: Russell E. Morris

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