The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles
Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

The homoleptic sandwich compounds-Mo and W biscorroles-have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.

1359-7345
5830-5833
Alemayehu, Abraham B.
87f64bd7-bb09-4f76-a631-b0991665ad3e
Vazquez-Lima, Hugo
e33ec9ee-1df4-4633-a970-eb464b54aa2f
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Ghosh, Abhik
01a311da-a139-43f0-ae29-0efa0e8788f7
Alemayehu, Abraham B.
87f64bd7-bb09-4f76-a631-b0991665ad3e
Vazquez-Lima, Hugo
e33ec9ee-1df4-4633-a970-eb464b54aa2f
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Ghosh, Abhik
01a311da-a139-43f0-ae29-0efa0e8788f7

Alemayehu, Abraham B., Vazquez-Lima, Hugo, McCormick, Laura J. and Ghosh, Abhik (2017) Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles. Chemical Communications, 53 (43), 5830-5833. (doi:10.1039/c7cc01549f).

Record type: Article

Abstract

The homoleptic sandwich compounds-Mo and W biscorroles-have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.

This record has no associated files available for download.

More information

Accepted/In Press date: 8 May 2017
e-pub ahead of print date: 12 May 2017
Published date: 28 May 2017

Identifiers

Local EPrints ID: 439018
URI: http://eprints.soton.ac.uk/id/eprint/439018
DOI: doi:10.1039/c7cc01549f
ISSN: 1359-7345
PURE UUID: b833028a-78cb-4dc0-a3f2-4bda1b615afb
ORCID for Laura J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717

Catalogue record

Date deposited: 01 Apr 2020 16:30
Last modified: 06 Jun 2024 02:08

Export record

Altmetrics

Contributors

Author: Abraham B. Alemayehu
Author: Hugo Vazquez-Lima
Author: Laura J. McCormick ORCID iD
Author: Abhik Ghosh

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×