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Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles
Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

The homoleptic sandwich compounds-Mo and W biscorroles-have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.

1359-7345
5830-5833
Alemayehu, Abraham B.
87f64bd7-bb09-4f76-a631-b0991665ad3e
Vazquez-Lima, Hugo
e33ec9ee-1df4-4633-a970-eb464b54aa2f
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Ghosh, Abhik
01a311da-a139-43f0-ae29-0efa0e8788f7
Alemayehu, Abraham B.
87f64bd7-bb09-4f76-a631-b0991665ad3e
Vazquez-Lima, Hugo
e33ec9ee-1df4-4633-a970-eb464b54aa2f
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Ghosh, Abhik
01a311da-a139-43f0-ae29-0efa0e8788f7

Alemayehu, Abraham B., Vazquez-Lima, Hugo, McCormick, Laura J. and Ghosh, Abhik (2017) Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles. Chemical Communications, 53 (43), 5830-5833. (doi:10.1039/c7cc01549f).

Record type: Article

Abstract

The homoleptic sandwich compounds-Mo and W biscorroles-have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.

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More information

Accepted/In Press date: 8 May 2017
e-pub ahead of print date: 12 May 2017
Published date: 28 May 2017

Identifiers

Local EPrints ID: 439018
URI: http://eprints.soton.ac.uk/id/eprint/439018
ISSN: 1359-7345
PURE UUID: b833028a-78cb-4dc0-a3f2-4bda1b615afb
ORCID for Laura J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717

Catalogue record

Date deposited: 01 Apr 2020 16:30
Last modified: 07 Oct 2020 02:27

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Contributors

Author: Abraham B. Alemayehu
Author: Hugo Vazquez-Lima
Author: Abhik Ghosh

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