The University of Southampton
University of Southampton Institutional Repository
Warning ePrints Soton is experiencing an issue with some file downloads not being available. We are working hard to fix this. Please bear with us.

Exploratory studies into 3d/4f cluster formation with fully bridge-substituted calix[4]arenes*

Exploratory studies into 3d/4f cluster formation with fully bridge-substituted calix[4]arenes*
Exploratory studies into 3d/4f cluster formation with fully bridge-substituted calix[4]arenes*

Calix[4]arenes are extremely versatile ligands that are capable of supporting the formation of a wide variety of polymetallic clusters of paramagnetic metal ions. One can exert influence over cluster formation through alteration of the calix[4]arene framework and subsequent ‘expansion’ of the lower-rim polyphenolic binding site. The present contribution investigates cluster formation with calix[4]arenes substituted at all four methylene bridge positions with furan moieties. Two known cluster types have been isolated with this ligand, the structures of which lend insight into factors that may ultimately preclude the formation of mixed-metal species.

Calixarenes, clusters, coordination chemistry, crystallography, synthesis
1061-0278
504-509
Fong, Angela
74fa1e8f-d37a-4c86-803d-abbac82335a5
McCormick, Laura
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
Brechin, Euan K.
3f928747-2144-43c3-8ac8-9b2013437edc
Dalgarno, Scott J.
9873ff1e-f5cb-4a5d-af3c-06c58655aab9
Fong, Angela
74fa1e8f-d37a-4c86-803d-abbac82335a5
McCormick, Laura
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Teat, Simon J.
fd6e6d90-b0c2-4463-91d2-5c72e212d414
Brechin, Euan K.
3f928747-2144-43c3-8ac8-9b2013437edc
Dalgarno, Scott J.
9873ff1e-f5cb-4a5d-af3c-06c58655aab9

Fong, Angela, McCormick, Laura, Teat, Simon J., Brechin, Euan K. and Dalgarno, Scott J. (2018) Exploratory studies into 3d/4f cluster formation with fully bridge-substituted calix[4]arenes*. Supramolecular Chemistry, 30 (5-6), 504-509. (doi:10.1080/10610278.2018.1430894).

Record type: Article

Abstract

Calix[4]arenes are extremely versatile ligands that are capable of supporting the formation of a wide variety of polymetallic clusters of paramagnetic metal ions. One can exert influence over cluster formation through alteration of the calix[4]arene framework and subsequent ‘expansion’ of the lower-rim polyphenolic binding site. The present contribution investigates cluster formation with calix[4]arenes substituted at all four methylene bridge positions with furan moieties. Two known cluster types have been isolated with this ligand, the structures of which lend insight into factors that may ultimately preclude the formation of mixed-metal species.

This record has no associated files available for download.

More information

Accepted/In Press date: 15 January 2018
e-pub ahead of print date: 1 February 2018
Published date: 3 June 2018
Additional Information: SI: Jerry Atwood 75th Birthday Special Issue
Keywords: Calixarenes, clusters, coordination chemistry, crystallography, synthesis

Identifiers

Local EPrints ID: 439031
URI: http://eprints.soton.ac.uk/id/eprint/439031
ISSN: 1061-0278
PURE UUID: cf190af9-c31a-445e-99ba-613f3dcc803b
ORCID for Laura McCormick: ORCID iD orcid.org/0000-0002-6634-4717

Catalogue record

Date deposited: 01 Apr 2020 16:32
Last modified: 07 Oct 2020 02:27

Export record

Altmetrics

Contributors

Author: Angela Fong
Author: Laura McCormick ORCID iD
Author: Simon J. Teat
Author: Euan K. Brechin
Author: Scott J. Dalgarno

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×