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Flexible organic light emitting diodes (OLEDs) based on a blue emitting polyfluorene

Flexible organic light emitting diodes (OLEDs) based on a blue emitting polyfluorene
Flexible organic light emitting diodes (OLEDs) based on a blue emitting polyfluorene

Flexible OLEDs were demonstrated using a highly efficient blue electroluminescent polyfluorene derivative. The flexible devices were fabricated on indium tin oxide (ITO) coated polyethylene terephthalate (PET) substrates with a sheet resistance of 35 Ω per sq. The emitting layer was poly[9,9-di-(2′-ethylhexyl)fluorenyl-2,7-diyl] (PF). A significant improvement of the luminance and device efficiency was achieved by confining the exciton formation zone within PF by two wide band-gap materials, namely PVK as a hole transport layer (HTL) and an inorganic oxide layer (IOL) as an electron transport and hole blocking layer. In order to achieve full-color LEDs based on a common host material, we probed the use of suitable dye emitters dispersed in PF at appropriate concentrations. The selection of the emitters is based on their capability to be effective energy transfer acceptors from the blue emitting PF. In particular, energy transfer was demonstrated from blue to green for PF-doped with the green dye emitter 1-[4-(dimethylamino)phenyl]-6- phenylhexa-1,3,5,-triene (DMA-DPH), and from blue to red for PF-doped with the red dye emitter (4-dimethylamino-4′-nitrostilbene) (DANS). This demonstration paves the way for developing highly efficient blue, green and red flexible OLEDs based on a common blue emitting PF host.

1862-6351
3658-3662
Vasilopoulou, M.
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Palilis, L. C.
b09e9554-54da-4be5-aa08-bda894e2b86f
Botsialas, A.
b23cb54a-8266-4389-b188-f96c206cd6d2
Georgiadou, D. G.
84977176-3678-4fb3-a3dd-2044a49c853b
Bayiati, P.
85e340c3-af21-4f7e-a0bc-121a35fed136
Vourdas, N.
10d8cfb5-6665-4a65-8b36-d9df0929a425
Petrou, P. S.
3d15fa2f-64e6-4d1d-a569-170855c9c957
Pistolis, G.
2a710db0-c97d-44bb-8ffc-896a7cd2a087
Stathopoulos, N. A.
83a4653f-c4c8-464a-8ed1-a93c52cf3833
Argitis, P.
ab9c4ea6-3dd2-4e34-935d-81bfb360f358
Vasilopoulou, M.
aad1381e-d091-4090-8c7c-b74bed22393d
Palilis, L. C.
b09e9554-54da-4be5-aa08-bda894e2b86f
Botsialas, A.
b23cb54a-8266-4389-b188-f96c206cd6d2
Georgiadou, D. G.
84977176-3678-4fb3-a3dd-2044a49c853b
Bayiati, P.
85e340c3-af21-4f7e-a0bc-121a35fed136
Vourdas, N.
10d8cfb5-6665-4a65-8b36-d9df0929a425
Petrou, P. S.
3d15fa2f-64e6-4d1d-a569-170855c9c957
Pistolis, G.
2a710db0-c97d-44bb-8ffc-896a7cd2a087
Stathopoulos, N. A.
83a4653f-c4c8-464a-8ed1-a93c52cf3833
Argitis, P.
ab9c4ea6-3dd2-4e34-935d-81bfb360f358

Vasilopoulou, M., Palilis, L. C., Botsialas, A., Georgiadou, D. G., Bayiati, P., Vourdas, N., Petrou, P. S., Pistolis, G., Stathopoulos, N. A. and Argitis, P. (2008) Flexible organic light emitting diodes (OLEDs) based on a blue emitting polyfluorene. Physica Status Solidi (C) Current Topics in Solid State Physics, 5 (12), 3658-3662. (doi:10.1002/pssc.200780214).

Record type: Article

Abstract

Flexible OLEDs were demonstrated using a highly efficient blue electroluminescent polyfluorene derivative. The flexible devices were fabricated on indium tin oxide (ITO) coated polyethylene terephthalate (PET) substrates with a sheet resistance of 35 Ω per sq. The emitting layer was poly[9,9-di-(2′-ethylhexyl)fluorenyl-2,7-diyl] (PF). A significant improvement of the luminance and device efficiency was achieved by confining the exciton formation zone within PF by two wide band-gap materials, namely PVK as a hole transport layer (HTL) and an inorganic oxide layer (IOL) as an electron transport and hole blocking layer. In order to achieve full-color LEDs based on a common host material, we probed the use of suitable dye emitters dispersed in PF at appropriate concentrations. The selection of the emitters is based on their capability to be effective energy transfer acceptors from the blue emitting PF. In particular, energy transfer was demonstrated from blue to green for PF-doped with the green dye emitter 1-[4-(dimethylamino)phenyl]-6- phenylhexa-1,3,5,-triene (DMA-DPH), and from blue to red for PF-doped with the red dye emitter (4-dimethylamino-4′-nitrostilbene) (DANS). This demonstration paves the way for developing highly efficient blue, green and red flexible OLEDs based on a common blue emitting PF host.

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More information

e-pub ahead of print date: 29 October 2008
Published date: 15 December 2008
Venue - Dates: 3rd International Conference on Micro-Nanoelectronics, Nanotechnology and MEMs, , Athens, Greece, 2007-11-18 - 2007-11-21

Identifiers

Local EPrints ID: 440502
URI: http://eprints.soton.ac.uk/id/eprint/440502
ISSN: 1862-6351
PURE UUID: 0329d82d-48e8-44e1-a40b-69fe4a2005da
ORCID for D. G. Georgiadou: ORCID iD orcid.org/0000-0002-2620-3346

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Date deposited: 06 May 2020 16:30
Last modified: 17 Mar 2024 04:00

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Contributors

Author: M. Vasilopoulou
Author: L. C. Palilis
Author: A. Botsialas
Author: P. Bayiati
Author: N. Vourdas
Author: P. S. Petrou
Author: G. Pistolis
Author: N. A. Stathopoulos
Author: P. Argitis

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