Crystal structure of N'-[4-(dimethylamino)benzyl-idene]furan-2-carbohydrazide monohydrate
Crystal structure of N'-[4-(dimethylamino)benzyl-idene]furan-2-carbohydrazide monohydrate
The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C
14H
15N
3O
2·H2O. The crystal packing is stabilized by intermolecular O(water)-H..O,N(carbohydrazide) and N-H..O(water) hydrogen bonds, which form a two-dimensional network along the bc plane. Additional C-H..O interactions link the molecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 14;(6)°. The carbohydrazide moiety, i.e., the C=N-N-C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 14;(9)° between their mean planes.
Crystal structure, furoic acid, hydrazide, hydrazone
660-663
Sylla-Gueye, Rokhaya
52a8975c-2b6c-455d-b69e-ecc79bf6368f
Thiam, Ibrahima Elhadji
e6458223-d3a8-4d23-a9fa-dacf54a959a6
Orton, James
4e2a471f-9e11-4cb4-abb6-d0398047939f
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gaye, Mohamed
e5a7f444-74c9-43ed-9323-69c883018ed6
1 May 2020
Sylla-Gueye, Rokhaya
52a8975c-2b6c-455d-b69e-ecc79bf6368f
Thiam, Ibrahima Elhadji
e6458223-d3a8-4d23-a9fa-dacf54a959a6
Orton, James
4e2a471f-9e11-4cb4-abb6-d0398047939f
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gaye, Mohamed
e5a7f444-74c9-43ed-9323-69c883018ed6
Sylla-Gueye, Rokhaya, Thiam, Ibrahima Elhadji, Orton, James, Coles, Simon J. and Gaye, Mohamed
(2020)
Crystal structure of N'-[4-(dimethylamino)benzyl-idene]furan-2-carbohydrazide monohydrate.
Acta Crystallographica Section E: Structure Reports Online, 76 (Part 5), .
(doi:10.1107/S205698902000465X).
Abstract
The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C
14H
15N
3O
2·H2O. The crystal packing is stabilized by intermolecular O(water)-H..O,N(carbohydrazide) and N-H..O(water) hydrogen bonds, which form a two-dimensional network along the bc plane. Additional C-H..O interactions link the molecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 14;(6)°. The carbohydrazide moiety, i.e., the C=N-N-C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 14;(9)° between their mean planes.
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More information
Accepted/In Press date: 3 April 2020
e-pub ahead of print date: 9 April 2020
Published date: 1 May 2020
Additional Information:
Publisher Copyright:
© 2020 International Union of Crystallography. All rights reserved.
Keywords:
Crystal structure, furoic acid, hydrazide, hydrazone
Identifiers
Local EPrints ID: 440770
URI: http://eprints.soton.ac.uk/id/eprint/440770
ISSN: 1600-5368
PURE UUID: 03c097a7-a855-471c-8e6b-6ace41234663
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Date deposited: 15 May 2020 16:57
Last modified: 17 Mar 2024 02:48
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Contributors
Author:
Rokhaya Sylla-Gueye
Author:
Ibrahima Elhadji Thiam
Author:
James Orton
Author:
Mohamed Gaye
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