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Crystal structure of N'-[4-(dimethylamino)benzyl-idene]furan-2-carbohydrazide monohydrate

Crystal structure of N'-[4-(dimethylamino)benzyl-idene]furan-2-carbohydrazide monohydrate
Crystal structure of N'-[4-(dimethylamino)benzyl-idene]furan-2-carbohydrazide monohydrate
The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethano yielded a yellow solid formulated as the title compound,C14H15N3O2H2O. The crystal packing is stabilized by intermolecular O(water)—H···O,N(carbohydrazide) and N—H···O(water) hydrogen bonds,which form a two-dimensional network along the bc plane. Additional C—H···O interactions link the molecules into a three-dimensional network. Thedihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)º. The carbohydrazide moiety,i.e., the C=N—N—C=O fragment andthe benzene ring are almost coplanar, with an angle of 6.75 (9)º between their mean planes.
Crystal structure, hydrazide, hydrazone, furoic acid
1600-5368
660-663
Sylla-Gueye, Rokhaya
52a8975c-2b6c-455d-b69e-ecc79bf6368f
Thiam, Ibrahima Elhadji
e6458223-d3a8-4d23-a9fa-dacf54a959a6
Orton, James
4e2a471f-9e11-4cb4-abb6-d0398047939f
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gaye, Mohamed
e5a7f444-74c9-43ed-9323-69c883018ed6
Sylla-Gueye, Rokhaya
52a8975c-2b6c-455d-b69e-ecc79bf6368f
Thiam, Ibrahima Elhadji
e6458223-d3a8-4d23-a9fa-dacf54a959a6
Orton, James
4e2a471f-9e11-4cb4-abb6-d0398047939f
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gaye, Mohamed
e5a7f444-74c9-43ed-9323-69c883018ed6

Sylla-Gueye, Rokhaya, Thiam, Ibrahima Elhadji, Orton, James, Coles, Simon J. and Gaye, Mohamed (2020) Crystal structure of N'-[4-(dimethylamino)benzyl-idene]furan-2-carbohydrazide monohydrate. Acta Crystallographica Section E: Structure Reports Online, 76 (Part 5), 660-663. (doi:10.1107/S205698902000465X).

Record type: Article

Abstract

The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethano yielded a yellow solid formulated as the title compound,C14H15N3O2H2O. The crystal packing is stabilized by intermolecular O(water)—H···O,N(carbohydrazide) and N—H···O(water) hydrogen bonds,which form a two-dimensional network along the bc plane. Additional C—H···O interactions link the molecules into a three-dimensional network. Thedihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)º. The carbohydrazide moiety,i.e., the C=N—N—C=O fragment andthe benzene ring are almost coplanar, with an angle of 6.75 (9)º between their mean planes.

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Accepted/In Press date: 3 April 2020
e-pub ahead of print date: 9 April 2020
Published date: May 2020
Keywords: Crystal structure, hydrazide, hydrazone, furoic acid

Identifiers

Local EPrints ID: 440770
URI: http://eprints.soton.ac.uk/id/eprint/440770
ISSN: 1600-5368
PURE UUID: 03c097a7-a855-471c-8e6b-6ace41234663
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 15 May 2020 16:57
Last modified: 30 Jun 2020 00:27

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