Supramolecular assemblies tailored by dipyridyl-1,2-4-thiadiazoles: influence of the building blocks in the predictability of the final network
Supramolecular assemblies tailored by dipyridyl-1,2-4-thiadiazoles: influence of the building blocks in the predictability of the final network
Coordinatively unsaturated dithiophosphato complex [Cd((MeO)
2PS
2)
2] (1) was reacted with the bifunctional ligands 3,5-di-(4-pyridyl)-1,2,4-thiadiazole (L1) and 3,5-di-(3-pyridyl)-1,2,4-thiadiazole (L2) to give the helicoidal coordination polymer (1·L1)
∞ and the paddle-wheel dimer (1·L2)
2, both characterised by single-crystal X-ray diffraction. A comparison of the structures with the different supramolecular constructs obtained by reacting L1 and L2 with differently P-substituted dithiophosphoric Ni
II complexes allowed to evaluate the role of the metal ion for the predictable assembly of this class of coordination polymers.
Supramolecular networks, XRD, cadmium, coordination polymers (CPs), dithiophosphates
267-275
Podda, Enrico
082cd7c4-4c31-47ba-a011-cc4d3126f02b
Arca, Massimiliano
f90b59f6-4dfb-471d-912e-3515e6507165
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Crespo Alonso, Miriam
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Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Pintus, Anna
d2ae260a-d159-48a7-b000-539e8c19c68e
Lippolis, Vito
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Carla Aragoni, M.
2aaa7a46-7c0a-45eb-a46b-3623db83407d
Podda, Enrico
082cd7c4-4c31-47ba-a011-cc4d3126f02b
Arca, Massimiliano
f90b59f6-4dfb-471d-912e-3515e6507165
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Crespo Alonso, Miriam
14268c27-dd92-499a-9573-e553b6b2aac3
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Pintus, Anna
d2ae260a-d159-48a7-b000-539e8c19c68e
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5
Carla Aragoni, M.
2aaa7a46-7c0a-45eb-a46b-3623db83407d
Podda, Enrico, Arca, Massimiliano, Coles, Simon J., Crespo Alonso, Miriam, Isaia, Francesco, Pintus, Anna, Lippolis, Vito and Carla Aragoni, M.
(2020)
Supramolecular assemblies tailored by dipyridyl-1,2-4-thiadiazoles: influence of the building blocks in the predictability of the final network.
Supramolecular Chemistry, 32 (4), .
(doi:10.1080/10610278.2020.1749275).
Abstract
Coordinatively unsaturated dithiophosphato complex [Cd((MeO)
2PS
2)
2] (1) was reacted with the bifunctional ligands 3,5-di-(4-pyridyl)-1,2,4-thiadiazole (L1) and 3,5-di-(3-pyridyl)-1,2,4-thiadiazole (L2) to give the helicoidal coordination polymer (1·L1)
∞ and the paddle-wheel dimer (1·L2)
2, both characterised by single-crystal X-ray diffraction. A comparison of the structures with the different supramolecular constructs obtained by reacting L1 and L2 with differently P-substituted dithiophosphoric Ni
II complexes allowed to evaluate the role of the metal ion for the predictable assembly of this class of coordination polymers.
Text
Final_Tinder_Tnader_Cd manuscript
- Accepted Manuscript
More information
Accepted/In Press date: 21 March 2020
e-pub ahead of print date: 19 April 2020
Additional Information:
Funding Information:
Fondazione di Sardegna (FdS) – Progetti biennali d’Ateneo annualità 2018 – and Università degli Studi di Cagliari are kindly acknowledge for financial support.
Publisher Copyright:
© 2020, © 2020 Informa UK Limited, trading as Taylor & Francis Group.
Keywords:
Supramolecular networks, XRD, cadmium, coordination polymers (CPs), dithiophosphates
Identifiers
Local EPrints ID: 441030
URI: http://eprints.soton.ac.uk/id/eprint/441030
ISSN: 1061-0278
PURE UUID: bd4cec2f-1df5-442a-bf2f-8fb7d78dc193
Catalogue record
Date deposited: 27 May 2020 16:56
Last modified: 17 Mar 2024 05:34
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Contributors
Author:
Enrico Podda
Author:
Massimiliano Arca
Author:
Miriam Crespo Alonso
Author:
Francesco Isaia
Author:
Anna Pintus
Author:
Vito Lippolis
Author:
M. Carla Aragoni
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