Near-field spectroscopy of cylindrical phonon-polariton antennas
Near-field spectroscopy of cylindrical phonon-polariton antennas
 
  Surface phonon polaritons (SPhPs) are hybrid light–matter states in which light strongly couples to lattice vibrations inside the Reststrahlen band of polar dielectrics at mid-infrared frequencies. Antennas supporting localized surface phonon polaritons (LSPhPs) easily outperform their plasmonic counterparts operating in the visible or near-infrared in terms of field enhancement and confinement thanks to the inherently slower phonon–phonon scattering processes governing SPhP decay. In particular, LSPhP antennas have attracted considerable interest for thermal management at the nanoscale, where the emission strongly diverts from the usual far-field blackbody radiation due to the presence of evanescent waves at the surface. However, far-field measurements cannot shed light on the behavior of antennas in the near-field region. To overcome this limitation, we employ scattering-scanning near-field optical microscopy (sSNOM) to unveil the spectral near-field response of 3C-SiC antenna arrays. We present a detailed description of the behavior of the antenna resonances by comparing far-field and near-field spectra and demonstrate the existence of a mode with no net dipole moment, absent in the far-field spectra, but of importance for applications that exploit the heightened electromagnetic near fields. Furthermore, we investigate the perturbation in the antenna response induced by the presence of the AFM tip, which can be further extended toward situations where for example strong IR emitters couple to LSPhP modes.
  dark mode, localized surface phonon polaritons, mid-infrared, near-field spectroscopy, silicon carbide
  
  
  8508-8517
  
    
      Mancini, Andrea
      
        17b367f1-e0e8-49f1-9298-9540725e182f
      
     
  
    
      Gubbin, Christopher
      
        09b75073-7a9a-4443-9a84-1458ec2535e9
      
     
  
    
      Berté, Rodrigo
      
        6110e8e5-7ad2-4efc-b333-fca479db8460
      
     
  
    
      Martini, Francesco
      
        394af6a7-dbcf-4d7b-9add-f7ed80bfe020
      
     
  
    
      Politi, Alberto
      
        cf75c0a8-d34d-4cbe-b9d5-e408c0edeeec
      
     
  
    
      Cortés, Emiliano
      
        403fa2c4-dd8e-44a3-bc87-6330f9895921
      
     
  
    
      Li, Yi
      
        2ba70794-b4aa-46d1-b7d0-c21a8fc68bdb
      
     
  
    
      De Liberato, Simone
      
        5942e45f-3115-4027-8653-a82667ed8473
      
     
  
    
      Maier, Stefan A.
      
        950db919-e145-48b5-bd73-196de02e46fe
      
     
  
  
   
  
  
    
    
  
    
    
  
    
      28 July 2020
    
    
  
  
    
      Mancini, Andrea
      
        17b367f1-e0e8-49f1-9298-9540725e182f
      
     
  
    
      Gubbin, Christopher
      
        09b75073-7a9a-4443-9a84-1458ec2535e9
      
     
  
    
      Berté, Rodrigo
      
        6110e8e5-7ad2-4efc-b333-fca479db8460
      
     
  
    
      Martini, Francesco
      
        394af6a7-dbcf-4d7b-9add-f7ed80bfe020
      
     
  
    
      Politi, Alberto
      
        cf75c0a8-d34d-4cbe-b9d5-e408c0edeeec
      
     
  
    
      Cortés, Emiliano
      
        403fa2c4-dd8e-44a3-bc87-6330f9895921
      
     
  
    
      Li, Yi
      
        2ba70794-b4aa-46d1-b7d0-c21a8fc68bdb
      
     
  
    
      De Liberato, Simone
      
        5942e45f-3115-4027-8653-a82667ed8473
      
     
  
    
      Maier, Stefan A.
      
        950db919-e145-48b5-bd73-196de02e46fe
      
     
  
       
    
 
  
    
      
  
  
  
  
  
  
    Mancini, Andrea, Gubbin, Christopher, Berté, Rodrigo, Martini, Francesco, Politi, Alberto, Cortés, Emiliano, Li, Yi, De Liberato, Simone and Maier, Stefan A.
  
  
  
  
   
    (2020)
  
  
    
    Near-field spectroscopy of cylindrical phonon-polariton antennas.
  
  
  
  
    ACS Nano, 14 (7), .
  
   (doi:10.1021/acsnano.0c02784). 
  
  
   
  
  
  
  
  
   
  
    
    
      
        
          Abstract
          Surface phonon polaritons (SPhPs) are hybrid light–matter states in which light strongly couples to lattice vibrations inside the Reststrahlen band of polar dielectrics at mid-infrared frequencies. Antennas supporting localized surface phonon polaritons (LSPhPs) easily outperform their plasmonic counterparts operating in the visible or near-infrared in terms of field enhancement and confinement thanks to the inherently slower phonon–phonon scattering processes governing SPhP decay. In particular, LSPhP antennas have attracted considerable interest for thermal management at the nanoscale, where the emission strongly diverts from the usual far-field blackbody radiation due to the presence of evanescent waves at the surface. However, far-field measurements cannot shed light on the behavior of antennas in the near-field region. To overcome this limitation, we employ scattering-scanning near-field optical microscopy (sSNOM) to unveil the spectral near-field response of 3C-SiC antenna arrays. We present a detailed description of the behavior of the antenna resonances by comparing far-field and near-field spectra and demonstrate the existence of a mode with no net dipole moment, absent in the far-field spectra, but of importance for applications that exploit the heightened electromagnetic near fields. Furthermore, we investigate the perturbation in the antenna response induced by the presence of the AFM tip, which can be further extended toward situations where for example strong IR emitters couple to LSPhP modes.
         
      
      
        
          
            
  
    Text
 SiC_Pillars_near_field_draft
     - Accepted Manuscript
   
  
  
    
  
 
          
            
          
            
           
            
           
        
        
       
    
   
  
  
  More information
  
    
      Accepted/In Press date: 12 June 2020
 
    
      e-pub ahead of print date: 17 June 2020
 
    
      Published date: 28 July 2020
 
    
  
  
    
  
    
     
        Additional Information:
        Funding Information:
The authors acknowledge the Deutsche Forschungsgemeinschaft (e-Conversion, EXC 2089/1-390776260), the Bavarian Solar Energies Go Hybrid (SolTech) program, and the Center for NanoScience (CeNS). E.C. acknowledges the European Commission for the ERC starting Grant 802989 CATALIGHT. S.D.L. is a Royal Society Research Fellow. S.D.L. and C.G. acknowledge support from the Royal Society grant RGF\EA\181001. Y.L. acknowledges the funding received from the European Unions Framework Programme for Research and Innovation Horizon 2020 (20142020) under the Marie Skodowska-Curie Grant Agreement No. 754388 (LMU Research Fellows) and from LMUexcellent as part of LMU Munichs funding as University of Excellence within the framework of the German Excellence Strategy. We acknowledge support from the Southampton Nanofabrication Centre. F.M. acknowledges the support from the European Union under the project H2020-MSCA-IF-2017, no. 795923, SHAMROCK. S.A.M. also acknowledges the Lee-Lucas Chair in Physics.
Publisher Copyright:
Copyright © 2020 American Chemical Society.
      
    
  
    
  
    
  
    
  
    
     
        Keywords:
        dark mode, localized surface phonon polaritons, mid-infrared, near-field spectroscopy, silicon carbide
      
    
  
    
  
    
  
  
        Identifiers
        Local EPrints ID: 441778
        URI: http://eprints.soton.ac.uk/id/eprint/441778
        
          
        
        
        
          ISSN: 1936-0851
        
        
          PURE UUID: 1cd317dd-e45d-4212-9095-bcf7bf602e9c
        
  
    
        
          
        
    
        
          
            
              
            
          
        
    
        
          
        
    
        
          
            
          
        
    
        
          
            
              
            
          
        
    
        
          
        
    
        
          
        
    
        
          
            
              
            
          
        
    
        
          
        
    
  
  Catalogue record
  Date deposited: 26 Jun 2020 16:45
  Last modified: 12 Jun 2025 04:03
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      Contributors
      
          
          Author:
          
            
            
              Andrea Mancini
            
          
        
      
          
          Author:
          
            
              
              
                Christopher Gubbin
              
              
                 
              
            
            
          
         
      
          
          Author:
          
            
            
              Rodrigo Berté
            
          
        
      
          
          Author:
          
            
              
              
                Francesco Martini
              
              
            
            
          
        
      
        
      
          
          Author:
          
            
            
              Emiliano Cortés
            
          
        
      
          
          Author:
          
            
            
              Yi Li
            
          
        
      
        
      
          
          Author:
          
            
            
              Stefan A. Maier
            
          
        
      
      
      
    
  
   
  
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