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Coordination complexes and applications of transition metal sulfide and selenide halides

Coordination complexes and applications of transition metal sulfide and selenide halides
Coordination complexes and applications of transition metal sulfide and selenide halides

Metal chalcogenide halides are less studied analogues of metal oxide halides, where the oxido-group is replaced by heavier Group 16 elements, specifically sulfur, selenium or tellurium. This article reviews the chemistry of neutral ligand complexes of molecular chalcogenide halides of the d-block metals. The majority of these complexes contain the higher oxidation states of niobium, tantalum and tungsten, with more limited examples of titanium, molybdenum and vanadium compounds. The synthesis, structures and properties are described, and areas in need of further study identified. The recent application of several examples as low pressure chemical vapour deposition reagents for the production of thin films of semiconducting metal dichalcogenide materials is also discussed.

chalcogenide halides, selenide bromide, selenide chloride, sulfide bromide, sulfide chloride, sulfide fluoride
0010-8545
Greenacre, Victoria
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Levason, William
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Reid, Gillian
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Smith, Danielle E.
aae55f94-b99a-4e9f-9d1b-8bcd3f2a93b6
Greenacre, Victoria
c665a38b-0b1a-4671-ac75-bf0679dd1c57
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Smith, Danielle E.
aae55f94-b99a-4e9f-9d1b-8bcd3f2a93b6

Greenacre, Victoria, Levason, William, Reid, Gillian and Smith, Danielle E. (2020) Coordination complexes and applications of transition metal sulfide and selenide halides. Coordination Chemistry Reviews, 424, [213512]. (doi:10.1016/j.ccr.2020.213512).

Record type: Article

Abstract

Metal chalcogenide halides are less studied analogues of metal oxide halides, where the oxido-group is replaced by heavier Group 16 elements, specifically sulfur, selenium or tellurium. This article reviews the chemistry of neutral ligand complexes of molecular chalcogenide halides of the d-block metals. The majority of these complexes contain the higher oxidation states of niobium, tantalum and tungsten, with more limited examples of titanium, molybdenum and vanadium compounds. The synthesis, structures and properties are described, and areas in need of further study identified. The recent application of several examples as low pressure chemical vapour deposition reagents for the production of thin films of semiconducting metal dichalcogenide materials is also discussed.

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thio seleno halide review CCR finalversion - Accepted Manuscript
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Accepted/In Press date: 17 July 2020
e-pub ahead of print date: 11 August 2020
Published date: 1 December 2020
Additional Information: Funding Information: We thank Engineering and Physical Sciences Research Council (EPSRC) for support (EP/P025137/1 and EP/N509747/1). The figures showing X-ray structures were redrawn with data provided by the Cambridge Crystallographic Data Centre. Publisher Copyright: © 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
Keywords: chalcogenide halides, selenide bromide, selenide chloride, sulfide bromide, sulfide chloride, sulfide fluoride

Identifiers

Local EPrints ID: 443273
URI: http://eprints.soton.ac.uk/id/eprint/443273
ISSN: 0010-8545
PURE UUID: 0336315f-ed98-4ecf-b4ea-960839409a59
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 19 Aug 2020 16:32
Last modified: 17 Jul 2022 04:01

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Contributors

Author: Victoria Greenacre
Author: William Levason ORCID iD
Author: Gillian Reid ORCID iD
Author: Danielle E. Smith

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