Coordination complexes and applications of transition metal sulfide and selenide halides
Coordination complexes and applications of transition metal sulfide and selenide halides
Metal chalcogenide halides are less studied analogues of metal oxide halides, where the oxido-group is replaced by heavier Group 16 elements, specifically sulfur, selenium or tellurium. This article reviews the chemistry of neutral ligand complexes of molecular chalcogenide halides of the d-block metals. The majority of these complexes contain the higher oxidation states of niobium, tantalum and tungsten, with more limited examples of titanium and molybdenum and vanadium compounds. The synthesis, structures and properties are described, and areas in need of further studies identified. The recent application of several examples as low pressure chemical vapour deposition reagents for the production of thin films of semiconducting metal dichalcogenide materials is also discussed.
chalcogenide halides, selenide bromide, selenide chloride, sulfide bromide, sulfide chloride, sulfide fluoride
Greenacre, Victoria
c665a38b-0b1a-4671-ac75-bf0679dd1c57
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Smith, Danielle Emily
dca4b149-33c4-4bc6-9f67-3d46b862363c
Greenacre, Victoria
c665a38b-0b1a-4671-ac75-bf0679dd1c57
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Smith, Danielle Emily
dca4b149-33c4-4bc6-9f67-3d46b862363c
Greenacre, Victoria, Levason, William, Reid, Gillian and Smith, Danielle Emily
(2020)
Coordination complexes and applications of transition metal sulfide and selenide halides.
Coordination Chemistry Reviews, 424, [213512].
(doi:10.1016/j.ccr.2020.213512).
Abstract
Metal chalcogenide halides are less studied analogues of metal oxide halides, where the oxido-group is replaced by heavier Group 16 elements, specifically sulfur, selenium or tellurium. This article reviews the chemistry of neutral ligand complexes of molecular chalcogenide halides of the d-block metals. The majority of these complexes contain the higher oxidation states of niobium, tantalum and tungsten, with more limited examples of titanium and molybdenum and vanadium compounds. The synthesis, structures and properties are described, and areas in need of further studies identified. The recent application of several examples as low pressure chemical vapour deposition reagents for the production of thin films of semiconducting metal dichalcogenide materials is also discussed.
Text
thio seleno halide review CCR finalversion
- Accepted Manuscript
Restricted to Repository staff only until 17 July 2022.
Request a copy
More information
Accepted/In Press date: 17 July 2020
e-pub ahead of print date: 11 August 2020
Keywords:
chalcogenide halides, selenide bromide, selenide chloride, sulfide bromide, sulfide chloride, sulfide fluoride
Identifiers
Local EPrints ID: 443273
URI: http://eprints.soton.ac.uk/id/eprint/443273
ISSN: 0010-8545
PURE UUID: 0336315f-ed98-4ecf-b4ea-960839409a59
Catalogue record
Date deposited: 19 Aug 2020 16:32
Last modified: 15 Sep 2021 01:37
Export record
Altmetrics
Contributors
Author:
Victoria Greenacre
Author:
Danielle Emily Smith
University divisions
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics