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Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2)•C6H6

Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2)•C6H6
Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2)•C6H6
Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V) was prepared by dropwise addition of an ethanolic solution of the ammonium salt of O,O-dimethyldithio-phosphoric acid to a hot aqueous solution of MoCl5. The X-ray structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2)•C6H6 was determined. Crystal data: Monoclinic, P2(1)/n, a = 6.9788(6), b = 22.616(3), c = 14.633(1) angstrom, beta = 101.193(9)degrees, V = 2265.5(4) angstrom(3), Z = 4. The immediate environment around the two molybdenum atoms is essentially square pyramidal if the Mo-Mo interaction is ignored. The terminal oxygen atoms are in the syn conformation.
molybdenum, methyl, dithiophosphate spectroscopic characterization, oxomolybdenum(iv) complexes, mo(v) complexes, chemistry, ligand, electrochemistry, dithiocarbonate, atom
1074-1542
135-140
Awwal, L.
ce39bba2-fa4e-4cce-bd9e-832fb2f495ab
Bingham, A.L.
8349446d-f3ab-4a2c-9b7b-88b01a9f59c0
Drake, J.E.
cf5a2c45-a2cb-4361-8b31-f2295e2050b7
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Kumar, R.
74dee938-14d6-4728-b727-e15fbb5b35b9
Ratnani, R.
5c33e340-5b43-4fae-b43d-c37ae26100ff
Awwal, L.
ce39bba2-fa4e-4cce-bd9e-832fb2f495ab
Bingham, A.L.
8349446d-f3ab-4a2c-9b7b-88b01a9f59c0
Drake, J.E.
cf5a2c45-a2cb-4361-8b31-f2295e2050b7
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Kumar, R.
74dee938-14d6-4728-b727-e15fbb5b35b9
Ratnani, R.
5c33e340-5b43-4fae-b43d-c37ae26100ff

Awwal, L., Bingham, A.L., Drake, J.E., Hursthouse, M.B., Light, M.E., Kumar, R. and Ratnani, R. (2006) Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2)•C6H6. Journal of Chemical Crystallography, 36 (2), 135-140. (doi:10.1007/s10870-005-9030-z).

Record type: Article

Abstract

Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V) was prepared by dropwise addition of an ethanolic solution of the ammonium salt of O,O-dimethyldithio-phosphoric acid to a hot aqueous solution of MoCl5. The X-ray structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2)•C6H6 was determined. Crystal data: Monoclinic, P2(1)/n, a = 6.9788(6), b = 22.616(3), c = 14.633(1) angstrom, beta = 101.193(9)degrees, V = 2265.5(4) angstrom(3), Z = 4. The immediate environment around the two molybdenum atoms is essentially square pyramidal if the Mo-Mo interaction is ignored. The terminal oxygen atoms are in the syn conformation.

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More information

Published date: 2006
Keywords: molybdenum, methyl, dithiophosphate spectroscopic characterization, oxomolybdenum(iv) complexes, mo(v) complexes, chemistry, ligand, electrochemistry, dithiocarbonate, atom

Identifiers

Local EPrints ID: 44368
URI: https://eprints.soton.ac.uk/id/eprint/44368
ISSN: 1074-1542
PURE UUID: 5fe24350-12bb-4268-83f2-993a71dc4b65
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 28 Feb 2007
Last modified: 14 Mar 2019 01:48

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