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Synthesis and X-ray characterization of the organotriboroxinate salts [Me3NCH2CH2OH][Ph4B3O3] and [NEt3H][Ph3B3O3(OH)], and the X-ray structure of the triarylboroxine, (4-MeOC6H4)(3)B3O3

Synthesis and X-ray characterization of the organotriboroxinate salts [Me3NCH2CH2OH][Ph4B3O3] and [NEt3H][Ph3B3O3(OH)], and the X-ray structure of the triarylboroxine, (4-MeOC6H4)(3)B3O3
Synthesis and X-ray characterization of the organotriboroxinate salts [Me3NCH2CH2OH][Ph4B3O3] and [NEt3H][Ph3B3O3(OH)], and the X-ray structure of the triarylboroxine, (4-MeOC6H4)(3)B3O3
The synthesis and characterization of the organotriboroxinate salts [Me3NCH2CH2OH][B3O4Ph4] (1) and [NEt3H][B3O3Ph3(OH)] (3) are reported. Compound 3 contains the first example of a hybrid inorganic/organic triboroxinate anion. Compounds I and 3 have been structurally characterized by single-crystal X-ray diffraction studies, which reveal H-bond ion-pair interactions between anions and cations in both 1 and 3, and additional anion-anion H-bond interactions in 3. Compound 3 exists as a dimer in the solid-state. A single crystal X-ray diffraction study of the triarylboroxine, (4-MeOC6H4)(3)B3O3, is also reported.
boroxinate anions, boroxines, x-ray structures molecular-structure, amine adducts, crystal-structures, ring
0277-5387
1011-1016
Beckett, Michael A.
5b021ef6-fa5c-4f6d-9998-3313558f0dc1
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Fischer, Lars
9842cd0b-8b60-468b-9020-3480535803bd
Stiefvater-Thomas, Ben M.
584d9d51-bc15-41e5-8f91-55b3208c390e
Varma, K. Sukuma
efe16deb-8a97-40a0-b59a-adc924f9775f
Beckett, Michael A.
5b021ef6-fa5c-4f6d-9998-3313558f0dc1
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Fischer, Lars
9842cd0b-8b60-468b-9020-3480535803bd
Stiefvater-Thomas, Ben M.
584d9d51-bc15-41e5-8f91-55b3208c390e
Varma, K. Sukuma
efe16deb-8a97-40a0-b59a-adc924f9775f

Beckett, Michael A., Coles, Simon J., Light, Mark E., Fischer, Lars, Stiefvater-Thomas, Ben M. and Varma, K. Sukuma (2006) Synthesis and X-ray characterization of the organotriboroxinate salts [Me3NCH2CH2OH][Ph4B3O3] and [NEt3H][Ph3B3O3(OH)], and the X-ray structure of the triarylboroxine, (4-MeOC6H4)(3)B3O3. Polyhedron, 25 (4), 1011-1016. (doi:10.1016/j.poly.2005.11.032).

Record type: Article

Abstract

The synthesis and characterization of the organotriboroxinate salts [Me3NCH2CH2OH][B3O4Ph4] (1) and [NEt3H][B3O3Ph3(OH)] (3) are reported. Compound 3 contains the first example of a hybrid inorganic/organic triboroxinate anion. Compounds I and 3 have been structurally characterized by single-crystal X-ray diffraction studies, which reveal H-bond ion-pair interactions between anions and cations in both 1 and 3, and additional anion-anion H-bond interactions in 3. Compound 3 exists as a dimer in the solid-state. A single crystal X-ray diffraction study of the triarylboroxine, (4-MeOC6H4)(3)B3O3, is also reported.

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Published date: 2006
Keywords: boroxinate anions, boroxines, x-ray structures molecular-structure, amine adducts, crystal-structures, ring

Identifiers

Local EPrints ID: 44378
URI: http://eprints.soton.ac.uk/id/eprint/44378
ISSN: 0277-5387
PURE UUID: 43c5916e-055d-45bd-bf95-6cd4e1cd39fd
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 01 Mar 2007
Last modified: 29 Oct 2019 01:59

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