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Crystal Structure of bis(O,O '-neopentylene dithiophosphato)nickel(II) Ni[S2POCH2CMe2CH2O](2) and bis(O,O '-hexylene dithiophosphato)nickel(II) Ni[S2POCMe2CH2CHMeO](2)

Crystal Structure of bis(O,O '-neopentylene dithiophosphato)nickel(II) Ni[S2POCH2CMe2CH2O](2) and bis(O,O '-hexylene dithiophosphato)nickel(II) Ni[S2POCMe2CH2CHMeO](2)
Crystal Structure of bis(O,O '-neopentylene dithiophosphato)nickel(II) Ni[S2POCH2CMe2CH2O](2) and bis(O,O '-hexylene dithiophosphato)nickel(II) Ni[S2POCMe2CH2CHMeO](2)
Purple crystals of bis(O,O'-neopentylene dithiophosphato)nickel(II), Ni[S2POCH2CMe2CH2O](2) and bis(O,O'-hexylene dithiophosphato)nickel(II), Ni[S2POCMe2CH2CHMeO](2) were obtained by layering benzene solutions of the complexes with ether and maintaining the samples at room temperature. The molecular structures of Ni[S2POCH2CMe2CH2O](2) and Ni[S2POCMe2CH2CHMeO](2) were determined by single-crystal X-ray diffraction. Ni[S2POCH2CMe2CH2O](2) crystallizes as monoclinic in the space group P2(1)/c with cell parameters a = 7.051(2) angstrom, b = 6.453(2) angstrom, c = 19.686(6) angstrom, beta = 99.45(3)degrees, V = 883.6(5) angstrom(-3), Z = 2, R = 0.0251, R-w = 0.0599. Ni[S2POCMe2CH2CHMeO](2) crystallizes as triclinic in the space group P-1 with cell parameters a = 8.394(5) angstrom, b = 11.070(5) angstrom, c = 12.124(5) angstrom, alpha = 71.287(5)degrees, beta = 76.227(5)degrees, gamma = 88.319(5)degrees, V = 1035.0(9) angstrom(-3), Z = 2, R = 0.0655, R-w = 0.1545. In both complexes the environment around nickel is distorted square planar.
1074-1542
249-254
Bingham, A.L.
8349446d-f3ab-4a2c-9b7b-88b01a9f59c0
Drake, J.E.
cf5a2c45-a2cb-4361-8b31-f2295e2050b7
Saraswat, K.
110d29b2-cfeb-4b65-8e91-922157c785a7
Nirwan, M.
3075fd5e-d99a-421d-bf72-20624f97d8fe
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Ratnani, R.
5c33e340-5b43-4fae-b43d-c37ae26100ff
Bingham, A.L.
8349446d-f3ab-4a2c-9b7b-88b01a9f59c0
Drake, J.E.
cf5a2c45-a2cb-4361-8b31-f2295e2050b7
Saraswat, K.
110d29b2-cfeb-4b65-8e91-922157c785a7
Nirwan, M.
3075fd5e-d99a-421d-bf72-20624f97d8fe
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Ratnani, R.
5c33e340-5b43-4fae-b43d-c37ae26100ff

Bingham, A.L., Drake, J.E., Saraswat, K., Nirwan, M., Hursthouse, M.B., Light, M.E. and Ratnani, R. (2006) Crystal Structure of bis(O,O '-neopentylene dithiophosphato)nickel(II) Ni[S2POCH2CMe2CH2O](2) and bis(O,O '-hexylene dithiophosphato)nickel(II) Ni[S2POCMe2CH2CHMeO](2). Journal of Chemical Crystallography, 36 (4), 249-254. (doi:10.1007/s10870-005-9007-y).

Record type: Article

Abstract

Purple crystals of bis(O,O'-neopentylene dithiophosphato)nickel(II), Ni[S2POCH2CMe2CH2O](2) and bis(O,O'-hexylene dithiophosphato)nickel(II), Ni[S2POCMe2CH2CHMeO](2) were obtained by layering benzene solutions of the complexes with ether and maintaining the samples at room temperature. The molecular structures of Ni[S2POCH2CMe2CH2O](2) and Ni[S2POCMe2CH2CHMeO](2) were determined by single-crystal X-ray diffraction. Ni[S2POCH2CMe2CH2O](2) crystallizes as monoclinic in the space group P2(1)/c with cell parameters a = 7.051(2) angstrom, b = 6.453(2) angstrom, c = 19.686(6) angstrom, beta = 99.45(3)degrees, V = 883.6(5) angstrom(-3), Z = 2, R = 0.0251, R-w = 0.0599. Ni[S2POCMe2CH2CHMeO](2) crystallizes as triclinic in the space group P-1 with cell parameters a = 8.394(5) angstrom, b = 11.070(5) angstrom, c = 12.124(5) angstrom, alpha = 71.287(5)degrees, beta = 76.227(5)degrees, gamma = 88.319(5)degrees, V = 1035.0(9) angstrom(-3), Z = 2, R = 0.0655, R-w = 0.1545. In both complexes the environment around nickel is distorted square planar.

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Published date: 2006

Identifiers

Local EPrints ID: 44386
URI: https://eprints.soton.ac.uk/id/eprint/44386
ISSN: 1074-1542
PURE UUID: a5380ace-fe9a-49eb-b3af-04002d889bce
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 05 Mar 2007
Last modified: 14 Mar 2019 01:48

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