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Anion binding vs. deprotonation in colorimetric pyrrolylamidothiourea based anion sensors

Anion binding vs. deprotonation in colorimetric pyrrolylamidothiourea based anion sensors
Anion binding vs. deprotonation in colorimetric pyrrolylamidothiourea based anion sensors
A pyrrolylamidothiourea deprotonates in the presence of one equivalent of not only fluoride, but also acetate, benzoate or dihydrogen phosphate in DMSO solution with structural studies using synchrotron radiation confirming thiourea deprotonation in the solid state.
solid-state, fluoride, recognition, receptors, thiourea
1359-7345
965-967
Evans, Louise S.
c9b34cb4-14cc-4587-a145-abdb0a74ead7
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Quesada, Roberto
c7db6299-4eb5-490d-9e6b-be4b9fbc8ca9
Evans, Louise S.
c9b34cb4-14cc-4587-a145-abdb0a74ead7
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Quesada, Roberto
c7db6299-4eb5-490d-9e6b-be4b9fbc8ca9

Evans, Louise S., Gale, Philip A., Light, Mark E. and Quesada, Roberto (2006) Anion binding vs. deprotonation in colorimetric pyrrolylamidothiourea based anion sensors. Chemical Communications, (9), 965-967. (doi:10.1039/b517308f).

Record type: Article

Abstract

A pyrrolylamidothiourea deprotonates in the presence of one equivalent of not only fluoride, but also acetate, benzoate or dihydrogen phosphate in DMSO solution with structural studies using synchrotron radiation confirming thiourea deprotonation in the solid state.

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More information

Published date: 2006
Keywords: solid-state, fluoride, recognition, receptors, thiourea

Identifiers

Local EPrints ID: 44435
URI: http://eprints.soton.ac.uk/id/eprint/44435
ISSN: 1359-7345
PURE UUID: 5208e9d0-b57f-4abc-b51b-6d9d0aa83be1
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 28 Feb 2007
Last modified: 17 Dec 2019 01:54

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