Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems
Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems
A number of salt eutectics have shown non-ideal electrical conductivity on melting and solidification, indicating some overlap between regions of 'solid-like' and 'melt-like' conductivities. Solidified eutectics showed much higher conductivities than expected from the values of the component salts, which is attributed to higher interfacial areas between the salt phases formed on solidification, with ionic transport being facilitated in these regions, which would have relatively high disorder.
li2so4-li2co3 system, hypereutectic salt, mixtures
1245-1250
Eweka, E. I.
fd21a086-b1d0-42f8-9c3e-cbea5dabf718
Kerridge, D. H.
1c9092ce-78b9-469b-b657-f319fce31cd9
2006
Eweka, E. I.
fd21a086-b1d0-42f8-9c3e-cbea5dabf718
Kerridge, D. H.
1c9092ce-78b9-469b-b657-f319fce31cd9
Eweka, E. I. and Kerridge, D. H.
(2006)
Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems.
Solid State Ionics, 177 (15-16), .
(doi:10.1016/j.ssi.2006.04.048).
Abstract
A number of salt eutectics have shown non-ideal electrical conductivity on melting and solidification, indicating some overlap between regions of 'solid-like' and 'melt-like' conductivities. Solidified eutectics showed much higher conductivities than expected from the values of the component salts, which is attributed to higher interfacial areas between the salt phases formed on solidification, with ionic transport being facilitated in these regions, which would have relatively high disorder.
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Published date: 2006
Keywords:
li2so4-li2co3 system, hypereutectic salt, mixtures
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Local EPrints ID: 44436
URI: http://eprints.soton.ac.uk/id/eprint/44436
ISSN: 0167-2738
PURE UUID: ff4c5e40-2f57-42f7-b346-8e661378edd6
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Date deposited: 01 Mar 2007
Last modified: 15 Mar 2024 09:04
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Author:
E. I. Eweka
Author:
D. H. Kerridge
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