Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems


Eweka, E. I. and Kerridge, D. H. (2006) Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems Solid State Ionics, 177, (15-16), pp. 1245-1250. (doi:10.1016/j.ssi.2006.04.048).

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Description/Abstract

A number of salt eutectics have shown non-ideal electrical conductivity on melting and solidification, indicating some overlap between regions of 'solid-like' and 'melt-like' conductivities. Solidified eutectics showed much higher conductivities than expected from the values of the component salts, which is attributed to higher interfacial areas between the salt phases formed on solidification, with ionic transport being facilitated in these regions, which would have relatively high disorder.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/j.ssi.2006.04.048
ISSNs: 0167-2738 (print)
Keywords: li2so4-li2co3 system, hypereutectic salt, mixtures
Subjects:
ePrint ID: 44436
Date :
Date Event
2006Published
Date Deposited: 01 Mar 2007
Last Modified: 16 Apr 2017 18:44
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/44436

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