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Formation and X-ray crystal structures of neutral 3D networks by charge-assisted hydrogen bonds between tetrakis(thiourea)platinum(II) complexes and dicarboxylates

Formation and X-ray crystal structures of neutral 3D networks by charge-assisted hydrogen bonds between tetrakis(thiourea)platinum(II) complexes and dicarboxylates
Formation and X-ray crystal structures of neutral 3D networks by charge-assisted hydrogen bonds between tetrakis(thiourea)platinum(II) complexes and dicarboxylates
Five new complex salts [Pt(SC(NH2)(2))(4)][dc] (dc = adipate (1), isoplithalate (2), tereplithalate (3), 4,4'-biphenyldicarboxylate (4), 1,4-naphthalenedicarboxylate (5)) have been characterized by single-crystal X-ray diffraction. Thiourea-carboxylate interactions have proven to be a reliable supramolecular synthon, yielding in all the examples charge-assisted hydrogen-bonded 3D networks via N-H•••O interactions.
platinum complexes, crystal engineering, hydrogen bonds, crystal structures, dicarboxylates, supramolecular networks coordination-complexes, zinc, n, n'-dimethylurea, recognition, copper(ii), framework, polymers, ligands, salts
0277-5387
901-909
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Quesada, Roberto
c7db6299-4eb5-490d-9e6b-be4b9fbc8ca9
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Quesada, Roberto
c7db6299-4eb5-490d-9e6b-be4b9fbc8ca9

Gale, Philip A., Light, Mark E. and Quesada, Roberto (2006) Formation and X-ray crystal structures of neutral 3D networks by charge-assisted hydrogen bonds between tetrakis(thiourea)platinum(II) complexes and dicarboxylates. Polyhedron, 25 (4), 901-909. (doi:10.1016/j.poly.2005.10.007).

Record type: Article

Abstract

Five new complex salts [Pt(SC(NH2)(2))(4)][dc] (dc = adipate (1), isoplithalate (2), tereplithalate (3), 4,4'-biphenyldicarboxylate (4), 1,4-naphthalenedicarboxylate (5)) have been characterized by single-crystal X-ray diffraction. Thiourea-carboxylate interactions have proven to be a reliable supramolecular synthon, yielding in all the examples charge-assisted hydrogen-bonded 3D networks via N-H•••O interactions.

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More information

Published date: 2006
Keywords: platinum complexes, crystal engineering, hydrogen bonds, crystal structures, dicarboxylates, supramolecular networks coordination-complexes, zinc, n, n'-dimethylurea, recognition, copper(ii), framework, polymers, ligands, salts

Identifiers

Local EPrints ID: 44447
URI: http://eprints.soton.ac.uk/id/eprint/44447
ISSN: 0277-5387
PURE UUID: 32f948d6-7cc1-4e71-bfbb-a9eb5b9c904d
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 01 Mar 2007
Last modified: 03 Dec 2019 01:55

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