The University of Southampton
University of Southampton Institutional Repository

Efficient phenanthrene, helicene, and azahelicene syntheses

Efficient phenanthrene, helicene, and azahelicene syntheses
Efficient phenanthrene, helicene, and azahelicene syntheses
Homolytic aromatic substitution reactions are used for the efficient regioselective synthesis of helicenes, phenanthrenes, and azahelicenes. The use of halo and alkoxy substituents to control the stereochemical outcome of this approach and X-ray studies of the resulting helicenes are described (see structure; red O, gray C).
helicenes, homolytic aromatic substitution, polyaromatic compounds, protecting groups, radical cyclization intramolecular radical additions, chiral discrimination, asymmetric-synthesis, molecular-structure, circular-dichroism, wittig reaction, anion-radicals, photocyclization, quinolines, catalysis
1433-7851
2242-2245
Harrowven, David C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Guy, Ian L.
b7d1bed5-2418-43d4-bb05-1db8d1bcc2db
Nanson, Lana
45d26fc2-88f6-484a-9436-874e0c7f4d4d
Harrowven, David C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Guy, Ian L.
b7d1bed5-2418-43d4-bb05-1db8d1bcc2db
Nanson, Lana
45d26fc2-88f6-484a-9436-874e0c7f4d4d

Harrowven, David C., Guy, Ian L. and Nanson, Lana (2006) Efficient phenanthrene, helicene, and azahelicene syntheses. Angewandte Chemie International Edition, 45 (14), 2242-2245. (doi:10.1002/anie.200504287). (PMID:16506249)

Record type: Article

Abstract

Homolytic aromatic substitution reactions are used for the efficient regioselective synthesis of helicenes, phenanthrenes, and azahelicenes. The use of halo and alkoxy substituents to control the stereochemical outcome of this approach and X-ray studies of the resulting helicenes are described (see structure; red O, gray C).

Full text not available from this repository.

More information

Published date: 2006
Additional Information: Communication
Keywords: helicenes, homolytic aromatic substitution, polyaromatic compounds, protecting groups, radical cyclization intramolecular radical additions, chiral discrimination, asymmetric-synthesis, molecular-structure, circular-dichroism, wittig reaction, anion-radicals, photocyclization, quinolines, catalysis

Identifiers

Local EPrints ID: 44459
URI: http://eprints.soton.ac.uk/id/eprint/44459
ISSN: 1433-7851
PURE UUID: 8239928c-46a0-4a02-aa97-6afc3b0185cf
ORCID for David C. Harrowven: ORCID iD orcid.org/0000-0001-6730-3573

Catalogue record

Date deposited: 05 Mar 2007
Last modified: 17 Dec 2019 01:59

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×