The University of Southampton
University of Southampton Institutional Repository

Mesomorphic silver(I) complexes of polycatenar 2 '- and 3 '-stilbazoles. Crystal and molecular structure of 3,4-dimethoxy-3 '-stilbazole and of two silver triflate complexes

Mesomorphic silver(I) complexes of polycatenar 2 '- and 3 '-stilbazoles. Crystal and molecular structure of 3,4-dimethoxy-3 '-stilbazole and of two silver triflate complexes
Mesomorphic silver(I) complexes of polycatenar 2 '- and 3 '-stilbazoles. Crystal and molecular structure of 3,4-dimethoxy-3 '-stilbazole and of two silver triflate complexes
The synthesis of 3,4-dialkoxy and 3,4,5-trialkoxy derivatives of 2- and 3-stilbazole are reported along with their related complexes with silver dodecylsulphate and silver triflate. The single crystal structures of one ligand and two complexes are reported. While none of the complexes of the 2-stilbazoles is liquid-crystalline, several complexes of the 3-stilbazoles show columnar mesophases as characterised by polarised optical microscopy and X-ray diffraction. The liquid crystal phase behaviour is compared with that of the parent 4-stilbazole derivatives.
metallomesogen, silver, stilbazole, polycatenar, liquid crystal catalyzed vinylic substitution, bonded liquid-crystals, x-ray-diffraction, alkoxystilbazoles, mesogens, ligand, calamitics, mesophases, phasmids, columnar
0277-5387
307-324
Huck, Deborah M.
bd1af7a1-e1e6-4562-8204-4d90996565d2
Nguyen, H. Loc
ace36cf1-db32-4413-8a7d-b84abbc9ecb2
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Guillon, Daniel
0c0b5d6d-b39c-43f4-9ce6-20f9ce7a35be
Donnio, Bertrand
80680a83-a6e5-4398-bcd5-80fc0c19fb06
Bruce, Duncan W.
1796c2a0-111d-4c01-bf59-8407cdba8d57
Huck, Deborah M.
bd1af7a1-e1e6-4562-8204-4d90996565d2
Nguyen, H. Loc
ace36cf1-db32-4413-8a7d-b84abbc9ecb2
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Guillon, Daniel
0c0b5d6d-b39c-43f4-9ce6-20f9ce7a35be
Donnio, Bertrand
80680a83-a6e5-4398-bcd5-80fc0c19fb06
Bruce, Duncan W.
1796c2a0-111d-4c01-bf59-8407cdba8d57

Huck, Deborah M., Nguyen, H. Loc, Horton, Peter N., Hursthouse, Michael B., Guillon, Daniel, Donnio, Bertrand and Bruce, Duncan W. (2006) Mesomorphic silver(I) complexes of polycatenar 2 '- and 3 '-stilbazoles. Crystal and molecular structure of 3,4-dimethoxy-3 '-stilbazole and of two silver triflate complexes. Polyhedron, 25 (2), 307-324. (doi:10.1016/j.poly.2005.07.023).

Record type: Article

Abstract

The synthesis of 3,4-dialkoxy and 3,4,5-trialkoxy derivatives of 2- and 3-stilbazole are reported along with their related complexes with silver dodecylsulphate and silver triflate. The single crystal structures of one ligand and two complexes are reported. While none of the complexes of the 2-stilbazoles is liquid-crystalline, several complexes of the 3-stilbazoles show columnar mesophases as characterised by polarised optical microscopy and X-ray diffraction. The liquid crystal phase behaviour is compared with that of the parent 4-stilbazole derivatives.

Full text not available from this repository.

More information

Published date: 2006
Keywords: metallomesogen, silver, stilbazole, polycatenar, liquid crystal catalyzed vinylic substitution, bonded liquid-crystals, x-ray-diffraction, alkoxystilbazoles, mesogens, ligand, calamitics, mesophases, phasmids, columnar

Identifiers

Local EPrints ID: 44464
URI: http://eprints.soton.ac.uk/id/eprint/44464
ISSN: 0277-5387
PURE UUID: ca3b1719-c0a0-475a-a273-9aab28661a9e
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 01 Mar 2007
Last modified: 03 Dec 2019 01:54

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×