Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers


Levason, W., Ratnani, R., Reid, G. and Webster, M. (2006) Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers Inorganica Chimica Acta, 359, (14), pp. 4627-4630. (doi:10.1016/j.ica.2006.05.017).

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Description/Abstract

The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)(2)] center dot (15-crown-5) and [MoO2Cl2(H2O)(2)] center dot (H2O)(2) center dot (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) center dot (crown)](2)-[Mo6O19]. The structures of the three complexes are briefly discussed.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/j.ica.2006.05.017
ISSNs: 0020-1693 (print)
Keywords: molybdenum, crown ether, crystal structure, isopolyanions transition-metal complexes, crystal-structure, spectroscopic characterization, sphere coordination, scandium(iii), macrocycles, products, acid
Subjects:
ePrint ID: 44483
Date :
Date Event
2006Published
Date Deposited: 02 Mar 2007
Last Modified: 16 Apr 2017 18:44
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/44483

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