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Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers

Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers
Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers
The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)(2)] center dot (15-crown-5) and [MoO2Cl2(H2O)(2)] center dot (H2O)(2) center dot (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) center dot (crown)](2)-[Mo6O19]. The structures of the three complexes are briefly discussed.
molybdenum, crown ether, crystal structure, isopolyanions transition-metal complexes, crystal-structure, spectroscopic characterization, sphere coordination, scandium(iii), macrocycles, products, acid
0020-1693
4627-4630
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Ratnani, R.
5c33e340-5b43-4fae-b43d-c37ae26100ff
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Ratnani, R.
5c33e340-5b43-4fae-b43d-c37ae26100ff
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7

Levason, W., Ratnani, R., Reid, G. and Webster, M. (2006) Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers. Inorganica Chimica Acta, 359 (14), 4627-4630. (doi:10.1016/j.ica.2006.05.017).

Record type: Article

Abstract

The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)(2)] center dot (15-crown-5) and [MoO2Cl2(H2O)(2)] center dot (H2O)(2) center dot (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) center dot (crown)](2)-[Mo6O19]. The structures of the three complexes are briefly discussed.

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More information

Published date: 2006
Keywords: molybdenum, crown ether, crystal structure, isopolyanions transition-metal complexes, crystal-structure, spectroscopic characterization, sphere coordination, scandium(iii), macrocycles, products, acid

Identifiers

Local EPrints ID: 44483
URI: http://eprints.soton.ac.uk/id/eprint/44483
ISSN: 0020-1693
PURE UUID: 5cd5c678-8851-4189-a797-f013d73b08be
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for G. Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 02 Mar 2007
Last modified: 29 Oct 2019 02:11

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