The University of Southampton
University of Southampton Institutional Repository

Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers

Record type: Article

The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)(2)] center dot (15-crown-5) and [MoO2Cl2(H2O)(2)] center dot (H2O)(2) center dot (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) center dot (crown)](2)-[Mo6O19]. The structures of the three complexes are briefly discussed.

Full text not available from this repository.

Citation

Levason, W., Ratnani, R., Reid, G. and Webster, M. (2006) Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers Inorganica Chimica Acta, 359, (14), pp. 4627-4630. (doi:10.1016/j.ica.2006.05.017).

More information

Published date: 2006
Keywords: molybdenum, crown ether, crystal structure, isopolyanions transition-metal complexes, crystal-structure, spectroscopic characterization, sphere coordination, scandium(iii), macrocycles, products, acid

Identifiers

Local EPrints ID: 44483
URI: http://eprints.soton.ac.uk/id/eprint/44483
ISSN: 0020-1693
PURE UUID: 5cd5c678-8851-4189-a797-f013d73b08be
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971

Catalogue record

Date deposited: 02 Mar 2007
Last modified: 17 Jul 2017 15:14

Export record

Altmetrics

Contributors

Author: W. Levason ORCID iD
Author: R. Ratnani
Author: G. Reid
Author: M. Webster

University divisions


Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×