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1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me)

Record type: Article

The structures of the compounds 1,2-bis(diphenylphosphino)-benzene, C30H24P2, [2-(diphenylphosphino)phenyl] methyl-diphenylphosphonium iodide, C31H27P2+center dot I-, and [2-(dimethylphosphino) phenyl]trimethylphosphonium iodide, C11H19P2+center dot I-, show that quaternization only occurs at one P centre and results in significantly shorter P-C bonds and larger C-P-C angles, consistent with the formal oxidation from P-III to P-V.

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Citation

Levason, W., Reid, G. and Webster, M. (2006) 1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me) Acta Crystallographica Section C Crystal Structure Communications, 62, (7), O438-O440. (doi:10.1107/S0108270106015915).

More information

Published date: 2006

Identifiers

Local EPrints ID: 44485
URI: http://eprints.soton.ac.uk/id/eprint/44485
ISSN: 0108-2701
PURE UUID: bc626957-f143-4551-97fd-8ec73ec13708
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971

Catalogue record

Date deposited: 05 Mar 2007
Last modified: 17 Jul 2017 15:14

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Contributors

Author: W. Levason ORCID iD
Author: G. Reid
Author: M. Webster

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