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The first molecular charge transfer salt containing layers of an alkali metal

The first molecular charge transfer salt containing layers of an alkali metal
The first molecular charge transfer salt containing layers of an alkali metal
We report the first molecular charge transfer salt containing layers of Na+ within its lattice. From the crystal structure and from C=C and C-S bond lengths and Raman stretching ftequencies we obtain a formula ?'"-(BEDT-TTF)(9)[Fe((C2O4)(3)](8)Na-18(H2O)(24). The structure consists of alternating layers of BEDT-TTF, and layers comprising [Fe(C2O4)(3)](3-) Na+ and H2O. The packing of the layers follows the sequence ABCDABCDA as previously seen in the compound ?"-(BEDT-TTF)(4)[Fe(C2O4)(3)](2•)C(12)O(6)H(24•)9H(x)O(1).
bedt-ttf, nh4, h3o, fe, cr
417-420
Martin, Lee
40bf71a6-83ea-41de-a1ff-711043af2d00
Day, Peter
2eda54f4-9e67-4134-98a1-7fdf7c91be22
Horton, Peter
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Bingham, Ann
c72d2471-4f71-431b-b1ee-d16770404dfd
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Martin, Lee
40bf71a6-83ea-41de-a1ff-711043af2d00
Day, Peter
2eda54f4-9e67-4134-98a1-7fdf7c91be22
Horton, Peter
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Bingham, Ann
c72d2471-4f71-431b-b1ee-d16770404dfd
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Martin, Lee, Day, Peter, Horton, Peter, Bingham, Ann and Hursthouse, Michael B. (2006) The first molecular charge transfer salt containing layers of an alkali metal. Journal of Low Temperature Physics, 142 (3-4), 417-420. (doi:10.1007/s10909-006-9127-6).

Record type: Article

Abstract

We report the first molecular charge transfer salt containing layers of Na+ within its lattice. From the crystal structure and from C=C and C-S bond lengths and Raman stretching ftequencies we obtain a formula ?'"-(BEDT-TTF)(9)[Fe((C2O4)(3)](8)Na-18(H2O)(24). The structure consists of alternating layers of BEDT-TTF, and layers comprising [Fe(C2O4)(3)](3-) Na+ and H2O. The packing of the layers follows the sequence ABCDABCDA as previously seen in the compound ?"-(BEDT-TTF)(4)[Fe(C2O4)(3)](2•)C(12)O(6)H(24•)9H(x)O(1).

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More information

Published date: 2006
Keywords: bedt-ttf, nh4, h3o, fe, cr

Identifiers

Local EPrints ID: 44496
URI: http://eprints.soton.ac.uk/id/eprint/44496
PURE UUID: 9aae1677-9bd8-4f15-a45f-a960c9db5fe7
ORCID for Peter Horton: ORCID iD orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 08 Mar 2007
Last modified: 20 Jul 2019 01:08

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