Developments in the chemistry of stibine and bismuthine complexes
Developments in the chemistry of stibine and bismuthine complexes
New findings in the coordination chemistry of neutral stibine and bismuthine ligands are reviewed. The article describes new ligand syntheses, coordination complexes of d-block and p-block elements with halostibines, halobismuthines, tertiary monostibines, tertiary bismuthines, distibines and hybrid polydentates containing antimony or bismuth. Current views on the nature of the M-Sb(Bi) bonds based upon X-ray structural studies and DFT calculations are discussed. The new work distinguishing metal stibine complexes from the chemistry of lighter phosphorus or arsenic ligands including, µ2- and µ3-bridging stibines, hypervalency and the oxidation of metal-coordinated stibines to stiboranyl or stiborane complexes, is also presented. Emerging applications of metal stibine complexes in catalysis, as reagents for the deposition of electronic materials and as anion sensors are illustrated. Literature coverage is from 2006 - early 2020.
antimony ligands, stibines, bismuthines, distibines, hypervalency, non-innocent stibines
Greenacre, Victoria
c665a38b-0b1a-4671-ac75-bf0679dd1c57
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Greenacre, Victoria
c665a38b-0b1a-4671-ac75-bf0679dd1c57
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Greenacre, Victoria, Levason, William and Reid, Gillian
(2020)
Developments in the chemistry of stibine and bismuthine complexes.
Coordination Chemistry Reviews.
(In Press)
Abstract
New findings in the coordination chemistry of neutral stibine and bismuthine ligands are reviewed. The article describes new ligand syntheses, coordination complexes of d-block and p-block elements with halostibines, halobismuthines, tertiary monostibines, tertiary bismuthines, distibines and hybrid polydentates containing antimony or bismuth. Current views on the nature of the M-Sb(Bi) bonds based upon X-ray structural studies and DFT calculations are discussed. The new work distinguishing metal stibine complexes from the chemistry of lighter phosphorus or arsenic ligands including, µ2- and µ3-bridging stibines, hypervalency and the oxidation of metal-coordinated stibines to stiboranyl or stiborane complexes, is also presented. Emerging applications of metal stibine complexes in catalysis, as reagents for the deposition of electronic materials and as anion sensors are illustrated. Literature coverage is from 2006 - early 2020.
Text
SbBiversionR1.3.11.2020
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Accepted/In Press date: 4 November 2020
Keywords:
antimony ligands, stibines, bismuthines, distibines, hypervalency, non-innocent stibines
Identifiers
Local EPrints ID: 445001
URI: http://eprints.soton.ac.uk/id/eprint/445001
ISSN: 0010-8545
PURE UUID: be2710f4-b0cc-4dbd-be3b-e25644ef6674
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Date deposited: 17 Nov 2020 17:39
Last modified: 18 Feb 2021 16:41
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Author:
Victoria Greenacre
University divisions
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