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Manipulation of singlet order by field-cycling

Manipulation of singlet order by field-cycling
Manipulation of singlet order by field-cycling

This chapter reviews a simple method for the generation of singlet order in scalar coupled spin systems. The method relies on adiabatically changing the magnetic field strength. In particular, the case of slowly removing the sample from the main magnet is discussed. The theoretical concepts of such adiabatic transformations and field cycling procedures are discussed and applied to a weakly coupled two-spin-1/2 system at high magnetic fields. More involved experimental procedures involving larger spin systems will be briefly mentioned.

2044-253X
22
113-127
Royal Society of Chemistry
Bengs, C.
cd3282d0-27ad-444f-bcb4-70eeab0029b9
Pileio, Giuseppe
Bengs, C.
cd3282d0-27ad-444f-bcb4-70eeab0029b9
Pileio, Giuseppe

Bengs, C. (2020) Manipulation of singlet order by field-cycling. In, Pileio, Giuseppe (ed.) Long-lived Nuclear Spin Order: Theory and Applications. (HASH(0xce294c8), 22, 2020-January) 22 ed. Royal Society of Chemistry, pp. 113-127. (doi:10.1039/9781788019972-00113).

Record type: Book Section

Abstract

This chapter reviews a simple method for the generation of singlet order in scalar coupled spin systems. The method relies on adiabatically changing the magnetic field strength. In particular, the case of slowly removing the sample from the main magnet is discussed. The theoretical concepts of such adiabatic transformations and field cycling procedures are discussed and applied to a weakly coupled two-spin-1/2 system at high magnetic fields. More involved experimental procedures involving larger spin systems will be briefly mentioned.

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Published date: 15 April 2020

Identifiers

Local EPrints ID: 445099
URI: http://eprints.soton.ac.uk/id/eprint/445099
ISSN: 2044-253X
PURE UUID: 705a9763-f797-46a5-b365-31f475f81707

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Date deposited: 19 Nov 2020 17:32
Last modified: 27 Apr 2022 06:10

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Contributors

Author: C. Bengs
Editor: Giuseppe Pileio

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