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Self-assembly of halogen adducts of ester and carboxylic acid functionalised 1,3-dithiole-2-thiones

Self-assembly of halogen adducts of ester and carboxylic acid functionalised 1,3-dithiole-2-thiones
Self-assembly of halogen adducts of ester and carboxylic acid functionalised 1,3-dithiole-2-thiones
New halogen adducts of 1,3-dithiole-2-thione-4-carboxylic acid and dimethyl 1,3-dithiole-2-thione-4,5-dicarboxylate have been prepared and characterised by X-ray crystallographic studies. The adducts feature an array of intramolecular and intermolecular close contacts involving chalcogen-chalcogen, chalcogen-halogen and halogen-halogen interactions. Whilst these contacts are derived from the basic heterocyclic unit and the coordinated halogen molecules, the ester and acid functionalities provide a varied and rich array of hydrogen bonding motifs, which significantly enhance the long-range order of the supramolecular structures.
dihalogen adducts, supramolecular chemistry, x-ray crystallography x-ray-diffraction, interhalogens, dihalogens, molecules, selenium, sulfur, diiodine, database, crystal, complex
0277-5387
989-995
Skabara, Peter J.
7138e414-7d50-41c7-933e-0bccad2fa4cd
Berridge, Rory
6aa42596-b293-4914-a1eb-2a974e7f2ed4
Bricklebank, Neil
6e082c98-a747-4690-bb37-f05f24d621f5
Lath, Helena
0fd3095e-aeb1-4217-bb35-0fc8a395b02c
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Skabara, Peter J.
7138e414-7d50-41c7-933e-0bccad2fa4cd
Berridge, Rory
6aa42596-b293-4914-a1eb-2a974e7f2ed4
Bricklebank, Neil
6e082c98-a747-4690-bb37-f05f24d621f5
Lath, Helena
0fd3095e-aeb1-4217-bb35-0fc8a395b02c
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5

Skabara, Peter J., Berridge, Rory, Bricklebank, Neil, Lath, Helena, Coles, Simon J. and Horton, Peter N. (2006) Self-assembly of halogen adducts of ester and carboxylic acid functionalised 1,3-dithiole-2-thiones. Polyhedron, 25 (4), 989-995. (doi:10.1016/j.poly.2005.11.013).

Record type: Article

Abstract

New halogen adducts of 1,3-dithiole-2-thione-4-carboxylic acid and dimethyl 1,3-dithiole-2-thione-4,5-dicarboxylate have been prepared and characterised by X-ray crystallographic studies. The adducts feature an array of intramolecular and intermolecular close contacts involving chalcogen-chalcogen, chalcogen-halogen and halogen-halogen interactions. Whilst these contacts are derived from the basic heterocyclic unit and the coordinated halogen molecules, the ester and acid functionalities provide a varied and rich array of hydrogen bonding motifs, which significantly enhance the long-range order of the supramolecular structures.

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More information

Published date: 2006
Keywords: dihalogen adducts, supramolecular chemistry, x-ray crystallography x-ray-diffraction, interhalogens, dihalogens, molecules, selenium, sulfur, diiodine, database, crystal, complex

Identifiers

Local EPrints ID: 44548
URI: http://eprints.soton.ac.uk/id/eprint/44548
ISSN: 0277-5387
PURE UUID: 9efc439d-ecb5-4063-b214-e8fdf934c506
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 01 Mar 2007
Last modified: 03 Dec 2019 01:55

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