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Barrier layer induced switching stability in Ga:ZnO nanorods based electrochemical metallization memory

Barrier layer induced switching stability in Ga:ZnO nanorods based electrochemical metallization memory
Barrier layer induced switching stability in Ga:ZnO nanorods based electrochemical metallization memory
The effect of the TiW barrier layer on the switching properties of Ga-doped ZnO (GZO) nanorods based on Electrochemical Metallization Memory is investigated. Vertically wellaligned and uniform GZO nanorods having a diameter of approximately 35 nm are hydrothermally grown on a seeding layer of ZnO deposited on indium tin oxide (ITO) coated glass substrate, to fabricate Cu/TiW/nanorods/ITO/Glass devices. The remarkable enhancement in the memory window (on/off ratio) is achieved in the 5 nm TiW barrier layer embedded device. This device exhibits endurance of more than 103 cycles and a large memory window of ∼103. The conduction mechanism at different current regions is studied, and it is found that Schottky emission is dominated in the low field region. The TiW barrier layer helps to retain the Cu ions and control the Cu ions diffusion, hence control the filament growth into the resistive layer, confirmed from the X-ray photoelectron spectroscopy (XPS) analysis. This device is suitable for the future low power non-volatile memory devices.
1941-0085
764-768
Panda, Debashis
e94eb431-589e-4a0a-82b8-0647442c0c5f
Simanjuntak, Firman M.
a5b8dd07-002c-4520-9f67-2dc20d2ff0d5
Chandrasekaran, Sridhar
8aece1e1-b034-4f63-b0b1-f9b1e4490765
Pattanayak, Bhaskar
9dd68f79-9367-4ebd-9773-e963193c48ea
Singh, Pragya
8fb95fa7-5174-48d9-b5ed-29c5f2574c5c
Tseng, Tseung-Yuen
b25672b0-7cd2-4c52-bb91-14d56d2777a9
Panda, Debashis
e94eb431-589e-4a0a-82b8-0647442c0c5f
Simanjuntak, Firman M.
a5b8dd07-002c-4520-9f67-2dc20d2ff0d5
Chandrasekaran, Sridhar
8aece1e1-b034-4f63-b0b1-f9b1e4490765
Pattanayak, Bhaskar
9dd68f79-9367-4ebd-9773-e963193c48ea
Singh, Pragya
8fb95fa7-5174-48d9-b5ed-29c5f2574c5c
Tseng, Tseung-Yuen
b25672b0-7cd2-4c52-bb91-14d56d2777a9

Panda, Debashis, Simanjuntak, Firman M., Chandrasekaran, Sridhar, Pattanayak, Bhaskar, Singh, Pragya and Tseng, Tseung-Yuen (2020) Barrier layer induced switching stability in Ga:ZnO nanorods based electrochemical metallization memory. IEEE Transactions on Nanotechnology, 764-768. (doi:10.1109/TNANO.2020.3029588).

Record type: Article

Abstract

The effect of the TiW barrier layer on the switching properties of Ga-doped ZnO (GZO) nanorods based on Electrochemical Metallization Memory is investigated. Vertically wellaligned and uniform GZO nanorods having a diameter of approximately 35 nm are hydrothermally grown on a seeding layer of ZnO deposited on indium tin oxide (ITO) coated glass substrate, to fabricate Cu/TiW/nanorods/ITO/Glass devices. The remarkable enhancement in the memory window (on/off ratio) is achieved in the 5 nm TiW barrier layer embedded device. This device exhibits endurance of more than 103 cycles and a large memory window of ∼103. The conduction mechanism at different current regions is studied, and it is found that Schottky emission is dominated in the low field region. The TiW barrier layer helps to retain the Cu ions and control the Cu ions diffusion, hence control the filament growth into the resistive layer, confirmed from the X-ray photoelectron spectroscopy (XPS) analysis. This device is suitable for the future low power non-volatile memory devices.

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Published date: September 2020

Identifiers

Local EPrints ID: 448742
URI: http://eprints.soton.ac.uk/id/eprint/448742
ISSN: 1941-0085
PURE UUID: e0d01856-a765-412f-b55a-31819ca9af44
ORCID for Firman M. Simanjuntak: ORCID iD orcid.org/0000-0002-9508-5849

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Date deposited: 04 May 2021 16:47
Last modified: 17 Mar 2024 03:59

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Contributors

Author: Debashis Panda
Author: Firman M. Simanjuntak ORCID iD
Author: Sridhar Chandrasekaran
Author: Bhaskar Pattanayak
Author: Pragya Singh
Author: Tseung-Yuen Tseng

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