Rotaxane coII complexes as field‐induced single‐ion magnets

Accepted/In Press date: 26 April 2021

e-pub ahead of print date: 26 April 2021

Published date: 12 July 2021

Additional Information: Funding Information: This work was supported financially by the QMUL Materials Research Institute (studentship to M.C.), the Royal Society (Research Fellowship to S.M.G.; SERB co‐funded Newton International Fellowship to A.K.), the European Union (Marie Skłodowska‐Curie Fellowship 660731 to JEML), European Research Council (Consolidator Grant 724987 to SMG.), the China Scholarship Council (studentship to Z.Z.), Imperial College (Research Fellowship to J.E.M.L.), the EPSRC (EP/R029385/1 to R.C.O.), Leverhulme Trust (RPG‐2019‐122 to R.C.O.) and the DFG (INST 41/863‐1 and SL104/10‐1 to J.v.S.). This research utilized QMUL's Apocrita HPC facility and the IRIDIS High Performance Computing Facility (and associated support services) at the University of Southampton. The EPSRC National EPR Facility at Manchester is gratefully acknowledged for magnetic measurements. We thank Mr David Hunger for help in fitting the ac data. Data supporting this study are openly available from the University of Southampton repository at https://doi.org/10.5258/SOTON/D1846. Funding Information: This work was supported financially by the QMUL Materials Research Institute (studentship to M.C.), the Royal Society (Research Fellowship to S.M.G.; SERB co-funded Newton International Fellowship to A.K.), the European Union (Marie Sk?odowska-Curie Fellowship 660731 to JEML), European Research Council (Consolidator Grant 724987 to SMG.), the China Scholarship Council (studentship to Z.Z.), Imperial College (Research Fellowship to J.E.M.L.), the EPSRC (EP/R029385/1 to R.C.O.), Leverhulme Trust (RPG-2019-122 to R.C.O.) and the DFG (INST 41/863-1 and SL104/10-1 to J.v.S.). This research utilized QMUL's Apocrita HPC facility and the IRIDIS High Performance Computing Facility (and associated support services) at the University of Southampton. The EPSRC National EPR Facility at Manchester is gratefully acknowledged for magnetic measurements. We thank Mr David Hunger for help in fitting the ac data. Data supporting this study are openly available from the University of Southampton repository at https://doi.org/10.5258/SOTON/D1846. Publisher Copyright: © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH

Keywords: electron paramagnetic resonance, magnetism, rotaxanes, single ion magnets, zero-field splitting

Local EPrints ID: 449175

URI: http://eprints.soton.ac.uk/id/eprint/449175

DOI: doi:10.1002/anie.202103596

ISSN: 1433-7851

PURE UUID: 1f9bb1bd-cfd6-4f7c-a28f-69178289cfb4

ORCID for Graham Tizzard: orcid.org/0000-0002-1577-5779

ORCID for Stephen Michael Goldup: orcid.org/0000-0003-3781-0464

Date deposited: 18 May 2021 16:40

Last modified: 17 Mar 2024 02:53