READ ME File For 'Dataset for: Rotaxane CoII complexes as field‐induced single‐ion magnets'

Dataset DOI: 10.5258/SOTON/D1846 

ReadMe Author: S. M. Goldup, University of Southampton

This dataset supports the publication: Rotaxane CoII complexes as field‐induced single‐ion magnets
AUTHORS:Martina Cirulli, Enrico Salvadori, Zhi-Hui Zhang, Michael Dommett, Floriana Tuna, Heiko Bamberger, James E. M. Lewis, Amanpreet Kaur, Graham Tizzard, Joris van Slageren, Rachel Crespo-Otero,* Stephen M. Goldup,* and Maxie M. Roessler*
TITLE: Rotaxane CoII complexes as field‐induced single‐ion magnets
JOURNAL: Angewandte Chemie International Edition
PAPER DOI IF KNOWN: doi.org/10.1002/anie.202103596


This dataset contains:
Characterisation data (NMR, MS, x-ray) for ligands 2 and 3 and their Co(II) complexes.
EPR and magnetization data for the Co(II) complexes of ligands 1-3.
Model coordinates for de novo and x-ray derived structures

Magnetisatin data refers to figures:

Fig. 2  Summary of EPR spectroscopic data.
Fig. 3  Plot of cT vs. T for [Co(1)](ClO4 )2 (^), [Co(2)](ClO4 )2 (*), [Co(3)](ClO4)2 (~) at 1000 Oe (100 mT).
Fig. 4  Frequency dependence of the out-of-phase magnetic susceptibility of 2 at 1.8–10 K under an applied field of 250 mT

Date of data collection: 4/6/2021

Information about geographic location of data collection: Southampton, London, Stuttgart, Manchester

Licence: CC-BY

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Date that the file was created: June 2021