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First example of solid-state luminescent borasiloxane-based chiral helices assembled through N-B bonds

First example of solid-state luminescent borasiloxane-based chiral helices assembled through N-B bonds
First example of solid-state luminescent borasiloxane-based chiral helices assembled through N-B bonds
The reaction between differently substituted borasiloxanes and 2,5-bis(3-pyridylethynyl)thiophene provided the first example of luminescent borasiloxane-based chiral helices held together by N-B bonds. The starting building blocks and the helices were fully characterized, and the nature of the N-B bond rationalized by means of theoretical calculations.
1477-9226
3782-3785
Podda, Enrico
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Coles, Simon J.
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Horton, Peter N.
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Lickiss, Paul D.
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Bull, Okpara S.
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Orton, James B.
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Pintus, Anna
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Pugh, David
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Carla Aragoni, M.
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Davies, Robert P.
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Podda, Enrico
14a14e34-7d30-440d-83d6-004332a23a0e
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Lickiss, Paul D.
dc0ce1d4-daea-452f-b0ef-77c9c62c5df8
Bull, Okpara S.
d9c04b28-5354-46a2-866b-449b8dcf6dab
Orton, James B.
4e2a471f-9e11-4cb4-abb6-d0398047939f
Pintus, Anna
d2ae260a-d159-48a7-b000-539e8c19c68e
Pugh, David
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Carla Aragoni, M.
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Davies, Robert P.
37552576-6a8d-4dbc-af70-12870f40a048

Podda, Enrico, Coles, Simon J., Horton, Peter N., Lickiss, Paul D., Bull, Okpara S., Orton, James B., Pintus, Anna, Pugh, David, Carla Aragoni, M. and Davies, Robert P. (2021) First example of solid-state luminescent borasiloxane-based chiral helices assembled through N-B bonds. Dalton Transactions, 50 (11), 3782-3785. (doi:10.1039/d1dt00114k).

Record type: Article

Abstract

The reaction between differently substituted borasiloxanes and 2,5-bis(3-pyridylethynyl)thiophene provided the first example of luminescent borasiloxane-based chiral helices held together by N-B bonds. The starting building blocks and the helices were fully characterized, and the nature of the N-B bond rationalized by means of theoretical calculations.

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More information

Accepted/In Press date: 18 February 2021
e-pub ahead of print date: 22 February 2021
Published date: 21 March 2021
Additional Information: Publisher Copyright: © The Royal Society of Chemistry 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

Identifiers

Local EPrints ID: 450734
URI: http://eprints.soton.ac.uk/id/eprint/450734
ISSN: 1477-9226
PURE UUID: b24b810d-af4a-455b-8626-54cb49726138
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 09 Aug 2021 16:31
Last modified: 26 Nov 2021 02:43

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Contributors

Author: Enrico Podda
Author: Simon J. Coles ORCID iD
Author: Peter N. Horton ORCID iD
Author: Paul D. Lickiss
Author: Okpara S. Bull
Author: James B. Orton
Author: Anna Pintus
Author: David Pugh
Author: M. Carla Aragoni
Author: Robert P. Davies

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