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Novel TCNQ-stacking motifs in (12-Crown-4)-complexes of Alkali Metal TCNQ Salts

Novel TCNQ-stacking motifs in (12-Crown-4)-complexes of Alkali Metal TCNQ Salts
Novel TCNQ-stacking motifs in (12-Crown-4)-complexes of Alkali Metal TCNQ Salts
An investigation of the solid-state behaviour of five 12-crown-4 alkali metal TCNQ complexes, (12-crown-4)2LiTCNQ (1), (12-crown-4)2NaTCNQ (2), (12-crown-4)2Li(TCNQ)2 (3), (12-crown-4)2Na(TCNQ)2 (4), and (12-crown-4)2K(TCNQ)2 (5), reveals an unusual “cross-stich” packing motif with the extended face-to-face π-stacked TCNQ•‒ columns present in complexes 1 and 2. The effect of the presence of additional neutral TCNQ0 has also been explored.
1466-8033
Yan, Bingjia
f15338c5-af00-41cf-9bd5-95f5f30ca617
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Weston, Simon C.
a1f89a93-6d78-4204-a004-5fa6220660e9
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Yan, Bingjia
f15338c5-af00-41cf-9bd5-95f5f30ca617
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Weston, Simon C.
a1f89a93-6d78-4204-a004-5fa6220660e9
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56

Yan, Bingjia, Horton, Peter N., Weston, Simon C., Russell, Andrea E. and Grossel, Martin C. (2021) Novel TCNQ-stacking motifs in (12-Crown-4)-complexes of Alkali Metal TCNQ Salts. CrystEngComm. (doi:10.1039/D1CE01075A).

Record type: Article

Abstract

An investigation of the solid-state behaviour of five 12-crown-4 alkali metal TCNQ complexes, (12-crown-4)2LiTCNQ (1), (12-crown-4)2NaTCNQ (2), (12-crown-4)2Li(TCNQ)2 (3), (12-crown-4)2Na(TCNQ)2 (4), and (12-crown-4)2K(TCNQ)2 (5), reveals an unusual “cross-stich” packing motif with the extended face-to-face π-stacked TCNQ•‒ columns present in complexes 1 and 2. The effect of the presence of additional neutral TCNQ0 has also been explored.

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More information

Accepted/In Press date: 30 August 2021
e-pub ahead of print date: 31 August 2021

Identifiers

Local EPrints ID: 451182
URI: http://eprints.soton.ac.uk/id/eprint/451182
ISSN: 1466-8033
PURE UUID: 83113eec-8eb9-4e13-a325-d7ea0724fbf2
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016
ORCID for Andrea E. Russell: ORCID iD orcid.org/0000-0002-8382-6443
ORCID for Martin C. Grossel: ORCID iD orcid.org/0000-0001-7469-6854

Catalogue record

Date deposited: 14 Sep 2021 16:07
Last modified: 15 Sep 2021 01:44

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