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Diastereoselective preparation of cis-2-substituted 3-ethenyl prolines via [3,2]-sigmatropic rearrangements of didehydropiperidinium ylids

Diastereoselective preparation of cis-2-substituted 3-ethenyl prolines via [3,2]-sigmatropic rearrangements of didehydropiperidinium ylids
Diastereoselective preparation of cis-2-substituted 3-ethenyl prolines via [3,2]-sigmatropic rearrangements of didehydropiperidinium ylids
The [3,2]-sigmatropic rearrangements of N-(methoxy-carbonyl)methyl-N-methyl-1,2,3,6-tetrahydropyridinium bromide (1a) has been extrapolated to allow preparation of (+/-)-cis-2-aryl-3-ethenyl prolines. and certain spiro-prolines.
[3, 2]-sigmatropic rearrangements kainoids nmda amino-acids analogs antagonists derivatives
0936-5214
1208-1209
Hayes, Jerome F.
c8a8729f-4fda-43ed-ada7-e50bb50d8eca
Tavassoli, Ali
d561cf8f-2669-46b5-b6e1-2016c85d63b2
Sweeney, J.B.
c074346d-11b2-4b8b-a9fa-63435c1f9594
Hayes, Jerome F.
c8a8729f-4fda-43ed-ada7-e50bb50d8eca
Tavassoli, Ali
d561cf8f-2669-46b5-b6e1-2016c85d63b2
Sweeney, J.B.
c074346d-11b2-4b8b-a9fa-63435c1f9594

Hayes, Jerome F., Tavassoli, Ali and Sweeney, J.B. (2000) Diastereoselective preparation of cis-2-substituted 3-ethenyl prolines via [3,2]-sigmatropic rearrangements of didehydropiperidinium ylids. Synlett, (8), 1208-1209. (doi:10.1055/s-2000-6742).

Record type: Article

Abstract

The [3,2]-sigmatropic rearrangements of N-(methoxy-carbonyl)methyl-N-methyl-1,2,3,6-tetrahydropyridinium bromide (1a) has been extrapolated to allow preparation of (+/-)-cis-2-aryl-3-ethenyl prolines. and certain spiro-prolines.

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More information

Published date: 2000
Keywords: [3, 2]-sigmatropic rearrangements kainoids nmda amino-acids analogs antagonists derivatives

Identifiers

Local EPrints ID: 45317
URI: https://eprints.soton.ac.uk/id/eprint/45317
ISSN: 0936-5214
PURE UUID: 1d94f74e-c9b8-41cf-8377-0fcc2095fa00
ORCID for Ali Tavassoli: ORCID iD orcid.org/0000-0002-7420-5063

Catalogue record

Date deposited: 21 Mar 2007
Last modified: 14 Mar 2019 01:41

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