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Solid-state assemblies from pyridine-2,6-dicarboxylates: “changing the instruction set through hydration”

Solid-state assemblies from pyridine-2,6-dicarboxylates: “changing the instruction set through hydration”
Solid-state assemblies from pyridine-2,6-dicarboxylates: “changing the instruction set through hydration”
A novel dihydrate structure of pyridine-2,6-dicarboxylic (dipicolinic) acid is reported, found to demonstrate a different solid-state archetecture to that of the previously published monohydrate crystal. In addition, we report the crystal structure of a monohydrate of 4-chloro pyridine-2,6-dicarboxylic acid, which is also compared to the known dipicolinic acid monohydrate.
crystal engineering, hydrogen bonding, pyridine dicarboxylic acids
1466-8033
207-210
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Dwyer, Andrew N.
a8d19fdc-08a2-4bc0-902c-5fb1b0582fd9
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Orton, James B.
4e2a471f-9e11-4cb4-abb6-d0398047939f
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Dwyer, Andrew N.
a8d19fdc-08a2-4bc0-902c-5fb1b0582fd9
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Orton, James B.
4e2a471f-9e11-4cb4-abb6-d0398047939f

Grossel, Martin C., Dwyer, Andrew N., Hursthouse, Michael B. and Orton, James B. (2007) Solid-state assemblies from pyridine-2,6-dicarboxylates: “changing the instruction set through hydration”. CrystEngComm, 9 (9), 207-210. (doi:10.1039/b617051j).

Record type: Article

Abstract

A novel dihydrate structure of pyridine-2,6-dicarboxylic (dipicolinic) acid is reported, found to demonstrate a different solid-state archetecture to that of the previously published monohydrate crystal. In addition, we report the crystal structure of a monohydrate of 4-chloro pyridine-2,6-dicarboxylic acid, which is also compared to the known dipicolinic acid monohydrate.

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More information

Submitted date: 22 November 2006
Published date: 6 February 2007
Keywords: crystal engineering, hydrogen bonding, pyridine dicarboxylic acids
Organisations: Chemistry
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Identifiers

Local EPrints ID: 45378
URI: http://eprints.soton.ac.uk/id/eprint/45378
DOI: doi:10.1039/b617051j
ISSN: 1466-8033
PURE UUID: 7137da39-6462-4334-8880-a29a29f1e192
ORCID for Martin C. Grossel: ORCID iD orcid.org/0000-0001-7469-6854

Catalogue record

Date deposited: 26 Mar 2007
Last modified: 16 Mar 2024 02:44

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Contributors

Author: Martin C. Grossel ORCID iD
Author: Andrew N. Dwyer
Author: Michael B. Hursthouse
Author: James B. Orton

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