READ ME File For 'Selection and Characterisation of Weakly Coordinating Solvents for Semiconductor Electrodeposition'

Dataset DOI: 10.5258/SOTON/D2187 

Date that the file was created: March, 2022 

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GENERAL INFORMATION
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ReadMe Author: Alexander Black, University of Southampton [https://orcid.org/0000-0003-3001-3083]

Date of data collection: August 2018 to October 2021

Information about geographic location of data collection: 

Related projects:
ADEPT

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SHARING/ACCESS INFORMATION
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Licenses/restrictions placed on the data, or limitations of reuse:CC-BY

Recommended citation for the data:

This dataset supports the publication:
AUTHORS: Alexander W. Black, Philip N. Bartlett
TITLE: Selection and Characterisation of Weakly Coordinating Solvents for Semiconductor Electrodeposition
JOURNAL: Physical Chemistry Chemical Physics
PAPER DOI IF KNOWN: 10.1039/d2cp00696k

Links to other publicly accessible locations of the data: n/a

Links/relationships to ancillary or related data sets: n/a


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DATA & FILE OVERVIEW
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This dataset contains:

One .opju file containing data corresponding to each Figure in the manuscript where experimental data was acquired in individual books

Figure 2:

	Plots of double-layer capacitance as a function of potential for each solvent studied scanning in the positive direction

Figure 3:
	
	Microdisc voltammograms at three sizes of microelectrode in each solvent studied

Figure 4:

	Plots of the redox potential of cobaltocenium hexafluorophosphate as a function of a measure of polarity of the solvent

Figure 5: 

	Plots of the limiting current at a microelectrode as a function of microelectrode size in each solvent studied

Figure 6:

	Plots of diffusion coefficient as a function of viscosity for decamethylferrocene and cobaltocenium hexafluorophosphate in each solvent studied

Figure S1: 

	Cyclic voltammograms of the potential window in each solvent studied at macroelectrodes of platinum, gold and glassy carbon

Figure S3: 

	Plots of double-layer capacitance as a function of potential for each solvent studied scanning in the negative direction

Figure S4:

	Plots of peak current as a function of the square root of scan rate for decamethylferrocene and cobaltocenium hexafluorophosphate in each solvent studied

Figure S5:
	
	Macrosdisc cyclic voltammograms of decamethylferrocene and cobaltocenium hexafluorophosphate at electrodes of platinum, gold and glassy carbon in each solvent studied

Figure S6:

	Mass transport corrected Tafel plots of decamethylferrocene and cobaltocenium hexafluorophosphate at a microelectrode in each solvent studied
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METHODOLOGICAL INFORMATION
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Methods for processing the data: current data was divided by the surface area of the electrode to give plotted current density