READ ME File For 'Diffusion in Weakly Coordinating Solvents'
Dataset DOI: 10.5258/SOTON/D2211
Date that the file was created: May, 2022
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GENERAL INFORMATION
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ReadMe Author: Alexander Black, University of Southampton [https://orcid.org/0000-0003-3001-3083]
Date of data collection: August 2018 to June 2021
Information about geographic location of data collection:
Related projects:
ADEPT
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SHARING/ACCESS INFORMATION
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Licenses/restrictions placed on the data, or limitations of reuse: CC-BY
Recommended citation for the data:
This dataset supports the publication:
AUTHORS: Alexander W. Black, Wenjian Zhang, Gillian Reid, Philip N. Bartlett
TITLE: Diffusion in Weakly Coordinating Solvents
JOURNAL: Electrochimica Acta
PAPER DOI IF KNOWN: 10.1016/j.electacta.2022.140720
Links to other publicly accessible locations of the data: n/a
Links/relationships to ancillary or related data sets: n/a
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DATA & FILE OVERVIEW
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This dataset contains:
The data corresponding to each Figure in the manuscript. All graphical data is included in a single Excel file
Figure 1:
Microelectrode voltammograms of decamethylferrocenium hexafluorophosphate at three different sizes of microelectrode in each studied solvent
Figure 2:
Plots of the limiting current at a microelectrode for decamethylferrocenium hexafluorophosphate as a function of electrode size in each solvent studied
Figure 3:
Plot of experimental diffusion coefficient as a function of the inverse of viscosity for decamethylferrocene in each solvent studied
Figure 4:
Predicted maximum and minimum diffusion coefficients as a function of the inverse of viscosity for decamethylferrocene in literature solvents
Figure 5:
Plot of experimental diffusion coefficient as a function of the inverse of viscosity for decamethylferrocenium hexafluorophosphate and cobaltocenium hexafluorophosphate in each solvent studied
Figure 6:
Plot of experimental diffusion coefficient as a function of the inverse of viscosity for tetrabutylammonium tetrachloroantimonate and tetrabutylammonium tetrachlorobismuthate in each solvent studied
Figure S1:
Cyclic voltammograms at a 50 micron Pt working electrode of tetrabutylammonium tetrachloroantimonate and tetrabutylammonium tetrachlorobismuthate in DCM, oDCB and DCE
Figure S2:
Limiting current at different sizes of Pt microelectrode for a) tetrabutylammonium tetrachloroantimonate and b) tetrabutylammonium tetrachlorobismuthate in DCM, oDCB and DCE
Figure S3:
Images of the crystal structure of decamethylferrocene along with measured dimensions in the axial and equatorial views
S3a DMFc measurement equatorial.png
S3b DMFc measurement axial.png
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METHODOLOGICAL INFORMATION
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Methods for processing the data: current values were divided by the surface area of the electrode to give current density, which was then plotted