Stones, Peter Arthur (1986) New ring forming reactions. University of Southampton, Doctoral Thesis.
Abstract
Chapters One and Two cover our investigation into utilising MVK in a four-carbon ring expansion procedure, giving access to the macrocyclic ketones, via the 1-hydroxy-3-oxo-6-phenylsulphinylbicyclo[n.4.0]alkane, using cyclododecanone as substrate. The required hydroxysulphone fragmentation precursor was impossible to prepare either by the `one-pot
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