The use of supramolecular chemistry in dye delivery systems
The use of supramolecular chemistry in dye delivery systems
This thesis reports an investigation into supramolecular recognition of the sulfate/sulfonate oxoanionic group, a moiety present in the majority of reactive dyes. In the first section the problems associated with the use of reactive dyes in dyeing cotton fabrics together with a literature review of supramolecular approaches to anion recognition are discussed. Drawing on the current literature concerning anion recognition (in particular the recognition of phosphates), the main body of the thesis concerns the design and synthesis of several series of C-shaped (tweezer) and tripodal potential sulfate/sulfonate receptors. These receptors incorporate the H-bond donor groups guanidine and thiourea and to a lesser extent urea and amide functionalities. In addition the behaviour of potential tweezer-like receptor molecules based on s-triazine (derived from cyanuric chloride) has also been investigated.
The sulfate/sulfonate and related phosphonate association properties of these potential receptors have been studied. Particular emphasis has been placed on the solid-state supramolecular structures formed by these complexes as determined by single crystal X-ray structural studies, and several novel and revealing examples have been analysed in detail. NMR titration binding studies have also been undertaken in order to investigate the complexation behaviour of several receptors with "model dye" phosphonates and sulfonates in solution.
In addition a number of single crystal X-ray crystallographic studies were undertaken for other members of the Grossel research group during the course of this work, and the results of these structural studies are also reported.
University of Southampton
Merckel, Daniel A. S
3ba91499-9f0c-453f-a443-72f7ae8ad701
2002
Merckel, Daniel A. S
3ba91499-9f0c-453f-a443-72f7ae8ad701
Merckel, Daniel A. S
(2002)
The use of supramolecular chemistry in dye delivery systems.
University of Southampton, Doctoral Thesis.
Record type:
Thesis
(Doctoral)
Abstract
This thesis reports an investigation into supramolecular recognition of the sulfate/sulfonate oxoanionic group, a moiety present in the majority of reactive dyes. In the first section the problems associated with the use of reactive dyes in dyeing cotton fabrics together with a literature review of supramolecular approaches to anion recognition are discussed. Drawing on the current literature concerning anion recognition (in particular the recognition of phosphates), the main body of the thesis concerns the design and synthesis of several series of C-shaped (tweezer) and tripodal potential sulfate/sulfonate receptors. These receptors incorporate the H-bond donor groups guanidine and thiourea and to a lesser extent urea and amide functionalities. In addition the behaviour of potential tweezer-like receptor molecules based on s-triazine (derived from cyanuric chloride) has also been investigated.
The sulfate/sulfonate and related phosphonate association properties of these potential receptors have been studied. Particular emphasis has been placed on the solid-state supramolecular structures formed by these complexes as determined by single crystal X-ray structural studies, and several novel and revealing examples have been analysed in detail. NMR titration binding studies have also been undertaken in order to investigate the complexation behaviour of several receptors with "model dye" phosphonates and sulfonates in solution.
In addition a number of single crystal X-ray crystallographic studies were undertaken for other members of the Grossel research group during the course of this work, and the results of these structural studies are also reported.
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Published date: 2002
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Local EPrints ID: 464652
URI: http://eprints.soton.ac.uk/id/eprint/464652
PURE UUID: 471181da-0a5d-4e54-980e-a15902e61545
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Date deposited: 04 Jul 2022 23:54
Last modified: 16 Mar 2024 19:40
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Author:
Daniel A. S Merckel
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