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Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques

Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques
Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques
UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.
1359-7345
128-129
Tromp, Moniek
48c1ebbb-579c-42b6-83bb-7188c668b322
Siestma, Jelle R.A.
7b705c90-5ac2-4e89-9f7e-f97af89fba33
van Bokhoven, Jeroen A.
ec7aff15-a681-4ae8-9a76-52b23a149f6b
van Strijdonck, Gino P.F.
ab1a4dc5-7547-42e7-b440-38ea02d463d3
van Haaren, Richard J.
05f2d33e-0d69-4e75-bd60-6949f137036c
van de Eerden, Ad M.J.
9c29f0b6-2008-43f0-b300-ea2be46af85c
van Leeuwen, Piet W.N.M.
72be186e-52c4-47fc-a129-ddc1a8294fa4
Koningsberger, Diek C.
4b5f2fc7-cfc5-4eb2-acab-9e5e0d637639
Tromp, Moniek
48c1ebbb-579c-42b6-83bb-7188c668b322
Siestma, Jelle R.A.
7b705c90-5ac2-4e89-9f7e-f97af89fba33
van Bokhoven, Jeroen A.
ec7aff15-a681-4ae8-9a76-52b23a149f6b
van Strijdonck, Gino P.F.
ab1a4dc5-7547-42e7-b440-38ea02d463d3
van Haaren, Richard J.
05f2d33e-0d69-4e75-bd60-6949f137036c
van de Eerden, Ad M.J.
9c29f0b6-2008-43f0-b300-ea2be46af85c
van Leeuwen, Piet W.N.M.
72be186e-52c4-47fc-a129-ddc1a8294fa4
Koningsberger, Diek C.
4b5f2fc7-cfc5-4eb2-acab-9e5e0d637639

Tromp, Moniek, Siestma, Jelle R.A., van Bokhoven, Jeroen A., van Strijdonck, Gino P.F., van Haaren, Richard J., van de Eerden, Ad M.J., van Leeuwen, Piet W.N.M. and Koningsberger, Diek C. (2003) Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques. Chemical Communications, 2003 (1), 128-129. (doi:10.1039/b206758g).

Record type: Article

Abstract

UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.

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Published date: 2003

Identifiers

Local EPrints ID: 46516
URI: http://eprints.soton.ac.uk/id/eprint/46516
ISSN: 1359-7345
PURE UUID: f505eba0-92c6-4b4f-afc1-325342cd4b44

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Date deposited: 04 Jul 2007
Last modified: 15 Mar 2024 09:24

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Contributors

Author: Moniek Tromp
Author: Jelle R.A. Siestma
Author: Jeroen A. van Bokhoven
Author: Gino P.F. van Strijdonck
Author: Richard J. van Haaren
Author: Ad M.J. van de Eerden
Author: Piet W.N.M. van Leeuwen
Author: Diek C. Koningsberger

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