The synthesis of novel chiral transition metal complexes
The synthesis of novel chiral transition metal complexes
The synthesis of a variety of novel chiral annulated and C2-symmteric cyclopentadienyl ligands and the formation of a novel titanocene complex is described. Chapter 1 provides an introduction to the research, outlining the methodology and stating the aims of the project. A literature review of chiral annulated Cyclopentadienyl ligands and the use of Group IV metallocenes as chiral catalysts is in asymmetric synthesis is discussed. Chapter two deals with the development of a chiral double Michael addition reaction, via the synthesis of 4-substituted chiral cyclopentenones, the products of which are intended for use as chiral Cyclopentadienyl ligands. Chapter three introduces a novel C2-symmetric ligand design, and the synthesis thereof, whilst chapter 4 presents the complexation of the novel C2-symmetric ligand to form a titanocene complex. Experimental details are given in chapter 5.
University of Southampton
2003
Dossett, David Michael
(2003)
The synthesis of novel chiral transition metal complexes.
University of Southampton, Doctoral Thesis.
Record type:
Thesis
(Doctoral)
Abstract
The synthesis of a variety of novel chiral annulated and C2-symmteric cyclopentadienyl ligands and the formation of a novel titanocene complex is described. Chapter 1 provides an introduction to the research, outlining the methodology and stating the aims of the project. A literature review of chiral annulated Cyclopentadienyl ligands and the use of Group IV metallocenes as chiral catalysts is in asymmetric synthesis is discussed. Chapter two deals with the development of a chiral double Michael addition reaction, via the synthesis of 4-substituted chiral cyclopentenones, the products of which are intended for use as chiral Cyclopentadienyl ligands. Chapter three introduces a novel C2-symmetric ligand design, and the synthesis thereof, whilst chapter 4 presents the complexation of the novel C2-symmetric ligand to form a titanocene complex. Experimental details are given in chapter 5.
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Published date: 2003
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Local EPrints ID: 465250
URI: http://eprints.soton.ac.uk/id/eprint/465250
PURE UUID: 5f00a98d-2588-41e1-a3af-307095bb2895
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Date deposited: 05 Jul 2022 00:31
Last modified: 05 Jul 2022 04:40
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Author:
David Michael Dossett
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