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Coherence transfer selectivity in two-dimensional solid-state NMR

Coherence transfer selectivity in two-dimensional solid-state NMR
Coherence transfer selectivity in two-dimensional solid-state NMR
In solid-state NMR, recoupling sequences are often used as the mixing elements of two-dimensional pulse sequences. We show that in many cases, the commutation properties of the mixing Hamiltonian leads to selectivity in the allowed coherence transfer processes. This property may lead to enhanced resolution in the cross-peaks of two-dimensional solid-state NMR spectra.
0009-2614
515-523
Carravetta, Marina
1b12fa96-4a6a-4689-ab3b-ccc68f1d7691
Zhao, Xin
634e60cd-764f-48ab-9759-673fe78842d4
Bockmann, Anja
105af11a-9af5-4833-ae04-63f3100f253f
Levitt, Malcolm H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3
Carravetta, Marina
1b12fa96-4a6a-4689-ab3b-ccc68f1d7691
Zhao, Xin
634e60cd-764f-48ab-9759-673fe78842d4
Bockmann, Anja
105af11a-9af5-4833-ae04-63f3100f253f
Levitt, Malcolm H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3

Carravetta, Marina, Zhao, Xin, Bockmann, Anja and Levitt, Malcolm H. (2003) Coherence transfer selectivity in two-dimensional solid-state NMR. Chemical Physics Letters, 376 (3-4), 515-523. (doi:10.1016/S0009-2614(03)00944-8).

Record type: Article

Abstract

In solid-state NMR, recoupling sequences are often used as the mixing elements of two-dimensional pulse sequences. We show that in many cases, the commutation properties of the mixing Hamiltonian leads to selectivity in the allowed coherence transfer processes. This property may lead to enhanced resolution in the cross-peaks of two-dimensional solid-state NMR spectra.

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More information

Published date: 24 July 2003

Identifiers

Local EPrints ID: 46672
URI: https://eprints.soton.ac.uk/id/eprint/46672
ISSN: 0009-2614
PURE UUID: 91acc90d-8607-460d-ae6f-6c48a331088c
ORCID for Marina Carravetta: ORCID iD orcid.org/0000-0002-6296-2104
ORCID for Malcolm H. Levitt: ORCID iD orcid.org/0000-0001-9878-1180

Catalogue record

Date deposited: 13 Jul 2007
Last modified: 20 Jul 2019 01:06

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