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Long-lived nuclear spin states in the solution NMR of four-spin systems

Long-lived nuclear spin states in the solution NMR of four-spin systems
Long-lived nuclear spin states in the solution NMR of four-spin systems
The existence of long-lived nuclear spin states in four-spin systems is explored by solution-state NMR experiments. Long-lived states are proved to exist in three different natural product molecules, each containing either a AA?BB? or a AA?XX? proton spin system. The measured state lifetimes are between four and eight times the spin–lattice relaxation time constants.
relaxation, long-lived spin states, singlet states
353-357
Pileio, Giuseppe
13f78e66-0707-4438-b9c9-6dbd3eb7d4e8
Concistrè, Maria
4d926227-2c26-489b-ac6c-ccc1354c68db
Carravetta, Marina
1b12fa96-4a6a-4689-ab3b-ccc68f1d7691
Levitt, Malcolm H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3
Pileio, Giuseppe
13f78e66-0707-4438-b9c9-6dbd3eb7d4e8
Concistrè, Maria
4d926227-2c26-489b-ac6c-ccc1354c68db
Carravetta, Marina
1b12fa96-4a6a-4689-ab3b-ccc68f1d7691
Levitt, Malcolm H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3

Pileio, Giuseppe, Concistrè, Maria, Carravetta, Marina and Levitt, Malcolm H. (2006) Long-lived nuclear spin states in the solution NMR of four-spin systems. Journal of Magnetic Resonance, 182 (2), 353-357. (doi:10.1016/j.jmr.2006.06.034).

Record type: Article

Abstract

The existence of long-lived nuclear spin states in four-spin systems is explored by solution-state NMR experiments. Long-lived states are proved to exist in three different natural product molecules, each containing either a AA?BB? or a AA?XX? proton spin system. The measured state lifetimes are between four and eight times the spin–lattice relaxation time constants.

Full text not available from this repository.

More information

Published date: October 2006
Additional Information: Communication
Keywords: relaxation, long-lived spin states, singlet states

Identifiers

Local EPrints ID: 46684
URI: http://eprints.soton.ac.uk/id/eprint/46684
PURE UUID: 6e7d53a3-0f77-4ea0-83cb-a2ad42000e94
ORCID for Giuseppe Pileio: ORCID iD orcid.org/0000-0001-9223-3896
ORCID for Marina Carravetta: ORCID iD orcid.org/0000-0002-6296-2104
ORCID for Malcolm H. Levitt: ORCID iD orcid.org/0000-0001-9878-1180

Catalogue record

Date deposited: 12 Jul 2007
Last modified: 12 Nov 2019 01:52

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