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An [FeIII8] molecular oxyhydroxide

An [FeIII8] molecular oxyhydroxide
An [FeIII8] molecular oxyhydroxide

An [FeIII8] hexagonal bipyramid displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state of S = 10.

1477-9226
8945-8948
Cutler, Daniel J.
7a9d4cc6-b284-441b-ada4-46483f72ac05
Coletta, Marco
1508dd77-1fcd-4e9d-93a6-82393caaa524
Singh, Mukesh K.
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Canaj, Angelos B.
9a2d50ef-2454-4ce1-b227-b7875a8eabcb
McCormick, Laura J.
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Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Schnack, Jürgen
cf1109a6-df37-4468-b6df-744e87b865bf
Brechin, Euan K.
3f928747-2144-43c3-8ac8-9b2013437edc
Cutler, Daniel J.
7a9d4cc6-b284-441b-ada4-46483f72ac05
Coletta, Marco
1508dd77-1fcd-4e9d-93a6-82393caaa524
Singh, Mukesh K.
96d26393-8f74-4ac0-b2c7-e3c957d1b6df
Canaj, Angelos B.
9a2d50ef-2454-4ce1-b227-b7875a8eabcb
McCormick, Laura J.
f1c2f8cd-adcc-4bbf-9289-0b33a006d2bb
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Schnack, Jürgen
cf1109a6-df37-4468-b6df-744e87b865bf
Brechin, Euan K.
3f928747-2144-43c3-8ac8-9b2013437edc

Cutler, Daniel J., Coletta, Marco, Singh, Mukesh K., Canaj, Angelos B., McCormick, Laura J., Coles, Simon J., Schnack, Jürgen and Brechin, Euan K. (2022) An [FeIII8] molecular oxyhydroxide. Dalton Transactions, 51 (23), 8945-8948. (doi:10.1039/d2dt01477g).

Record type: Article

Abstract

An [FeIII8] hexagonal bipyramid displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state of S = 10.

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Accepted/In Press date: 18 May 2022
e-pub ahead of print date: 18 May 2022
Additional Information: Funding Information: E. K. B. thanks the EPSRC (EP/V010573/1). M. K. S. would like to thank Edinburgh Compute and Data Facility (ECDF), and the European Union Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement no. 832488. For the purpose of open access, the author has applied a Creative Commons Attribution (CC BY) license to any Author Accepted Manuscript version arising from this submission. Publisher Copyright: © 2022 The Royal Society of Chemistry

Identifiers

Local EPrints ID: 469994
URI: http://eprints.soton.ac.uk/id/eprint/469994
ISSN: 1477-9226
PURE UUID: 63ebe1fa-52a5-4c39-ad28-d6609344f47e
ORCID for Laura J. McCormick: ORCID iD orcid.org/0000-0002-6634-4717
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 29 Sep 2022 16:55
Last modified: 30 Sep 2022 02:00

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Contributors

Author: Daniel J. Cutler
Author: Marco Coletta
Author: Mukesh K. Singh
Author: Angelos B. Canaj
Author: Simon J. Coles ORCID iD
Author: Jürgen Schnack
Author: Euan K. Brechin

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