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Dielectric studies of polystyrene-based, high-permittivity composite systems

Dielectric studies of polystyrene-based, high-permittivity composite systems
Dielectric studies of polystyrene-based, high-permittivity composite systems
In this paper, we report on a dielectric study of a series of composite systems based upon a polystyrene matrix (εm ∼2.7) containing dispersed particles of lead zirconate titanate (PZT) and barium titanate (BaTiO3) (in both cases, εp ∼1000). These components were chosen to give a high dielectric contrast within the system and, because polystyrene is readily etched using permanganic reagents, the size and distribution of particles within the matrix could be readily determined by scanning electron microscopy. We report on the effect of composition on the effective permittivity of the composite; the precise composition of each system was determined by thermogravimetric analysis. The results obtained are compared with theoretical models. We show that, in systems with high dielectric contrast between the matrix and the particles, the variation in relative permittivity with filler loading is best described by the Lichtenecker Rother model.
711-714
IEEE
Topham, J.
170f6bd8-666b-49de-b1fa-c2b45380401e
Boorman, O.
c254a648-a5e3-43dd-b83f-0a354099da58
Hosier, I. L.
6a44329e-b742-44de-afa7-073f80a78e26
Praeger, M.
84575f28-4530-4f89-9355-9c5b6acc6cac
Torah, R.
7147b47b-db01-4124-95dc-90d6a9842688
Vaughan, A. S.
6d813b66-17f9-4864-9763-25a6d659d8a3
Andritsch, T.
8681e640-e584-424e-a1f1-0d8b713de01c
Swingler, S. G.
4f13fbb2-7d2e-480a-8687-acea6a4ed735
Topham, J.
170f6bd8-666b-49de-b1fa-c2b45380401e
Boorman, O.
c254a648-a5e3-43dd-b83f-0a354099da58
Hosier, I. L.
6a44329e-b742-44de-afa7-073f80a78e26
Praeger, M.
84575f28-4530-4f89-9355-9c5b6acc6cac
Torah, R.
7147b47b-db01-4124-95dc-90d6a9842688
Vaughan, A. S.
6d813b66-17f9-4864-9763-25a6d659d8a3
Andritsch, T.
8681e640-e584-424e-a1f1-0d8b713de01c
Swingler, S. G.
4f13fbb2-7d2e-480a-8687-acea6a4ed735

Topham, J., Boorman, O., Hosier, I. L., Praeger, M., Torah, R., Vaughan, A. S., Andritsch, T. and Swingler, S. G. (2014) Dielectric studies of polystyrene-based, high-permittivity composite systems. In IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2014. IEEE. pp. 711-714 . (doi:10.1109/CEIDP.2014.6995854).

Record type: Conference or Workshop Item (Paper)

Abstract

In this paper, we report on a dielectric study of a series of composite systems based upon a polystyrene matrix (εm ∼2.7) containing dispersed particles of lead zirconate titanate (PZT) and barium titanate (BaTiO3) (in both cases, εp ∼1000). These components were chosen to give a high dielectric contrast within the system and, because polystyrene is readily etched using permanganic reagents, the size and distribution of particles within the matrix could be readily determined by scanning electron microscopy. We report on the effect of composition on the effective permittivity of the composite; the precise composition of each system was determined by thermogravimetric analysis. The results obtained are compared with theoretical models. We show that, in systems with high dielectric contrast between the matrix and the particles, the variation in relative permittivity with filler loading is best described by the Lichtenecker Rother model.

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More information

Published date: 22 October 2014
Venue - Dates: 2014 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2014, , Des Moines, United States, 2014-10-19 - 2014-10-22

Identifiers

Local EPrints ID: 472392
URI: http://eprints.soton.ac.uk/id/eprint/472392
PURE UUID: 60ec82bc-881c-485e-b63a-f7d022e4ef3c
ORCID for I. L. Hosier: ORCID iD orcid.org/0000-0003-4365-9385
ORCID for M. Praeger: ORCID iD orcid.org/0000-0002-5814-6155
ORCID for R. Torah: ORCID iD orcid.org/0000-0002-5598-2860
ORCID for A. S. Vaughan: ORCID iD orcid.org/0000-0002-0535-513X
ORCID for T. Andritsch: ORCID iD orcid.org/0000-0002-3462-022X

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Date deposited: 05 Dec 2022 17:31
Last modified: 17 Mar 2024 03:33

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Contributors

Author: J. Topham
Author: O. Boorman
Author: I. L. Hosier ORCID iD
Author: M. Praeger ORCID iD
Author: R. Torah ORCID iD
Author: A. S. Vaughan ORCID iD
Author: T. Andritsch ORCID iD
Author: S. G. Swingler

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