EAD ME File For 'Temperature effects on the electrodeposition of semiconductors from a weakly coordinating solvent'

Dataset DOI: 10.5258/SOTON/D2648

Date that the file was created: May, 2023

-------------------
GENERAL INFORMATION
-------------------

ReadMe Author: Alexander Black, University of Southampton [https://orcid.org/0000-0003-3001-3083]

Date of data collection: January 2021 to December 2021

Information about geographic location of data collection: 

Related projects:
ADEPT

--------------------------
SHARING/ACCESS INFORMATION
-------------------------- 

Licenses/restrictions placed on the data, or limitations of reuse: CC-BY

Recommended citation for the data:

This dataset supports the publication:
AUTHORS: Alexander W. Black, Wenjian Zhang, Yasir J. Noori, Gillian Reid, Philip N. Bartlett
TITLE: Temperature effects on the electrodeposition of semiconductors from a weakly coordinating solvent
JOURNAL: Journal of Electroanalytical Chemistry
PAPER DOI IF KNOWN: https://doi.org/10.1016/j.jelechem.2023.117638


--------------------
DATA & FILE OVERVIEW
--------------------

This dataset contains:

All images and data corresponding to each Figure in the manuscript. All graphical data is included in a single Excel file

Figure 1:
	
	Plot showing the variation in half wave potential of decamethylferrocene as a function of temperature in the solvent o-dichlorobenzene

Figure 2:

	Voltammogram of antimony tetrachloride at a TiN working electrode in o-dichlorobenzene

Figure 3:

	SEM images of Sb electrodeposited onto TiN from o-dichlorobenzene at various temperatures
	
		Fig3_25.TIF
		Fig3_80.TIF
		Fig3_100.TIF
		Fig3_120.TIF
		Fig3_140.TIF

Figure 4:

	XRD patterns of Sb electrodeposited at various temperatures

Figure 5:

	Raman spectra of Sb electrodeposited at various temperatures

Figure 6:

	Voltammograms of antimony tetrachloride and tellurium hexachloride at a TiN working electrode in o-dichlorobenzene

Figure 7:

	The effect of temperature on the composition of antimony and tellurium electrodeposited from o-dichlorobenzene

Figure 8:

	SEM images of antimony telluride electrodeposited at different temperatures from o-dichlorobenzene

		Fig8_25.TIF
		Fig8_80.TIF
		Fig8_100.TIF
		Fig8_120.TIF

Figure 9:

	XRD patterns of antimony telluride electrodeposited at different temperatures from o-dichlorobenzene

Figure 10:

	Cross sectional z-profiles of antimony and antimony telluride electrodeposited at 25 and 120 Celsius from o-dichlorobenzene

Figure 11:

	The effect of heating to 140 Celsius on the voltammetry of antimony tetrachloride in o-dichlorobenzene

Figure S2:

	Voltammograms of decamethylferrocene at various temperatures at a Pt electrode in o-dichlorobenzene

Figure S3:

	Voltammograms of antimony tetrachloride at a TiN working electrode at 25 and 120 Celsius in o-dichlorobenzene

Figure S4:

	Extended depth of focus optical microscope image of antimony electrodeposited at 25 Celsius
		
		FigS4.TIFF

Figure S5:

	Extended depth of focus optical microscope image of antimony electrodeposited at 120 Celsius

		FigS5.TIFF

Figure S6:
	
	Extended depth of focus optical microscope image of antimony telluride electrodeposited at 25 Celsius

		FigS6.TIFF

Figure S7:

	Extended depth of focus optical microscope image of antimony telluride electrodeposited at 120 Celsius

		FigS7.TIFF

Figure S8:

	Height map optical microscope image of antimony electrodeposited at 25 Celsius
	
		FigS8.TIF

Figure S9:

	Height map optical microscope image of antimony electrodeposited at 120 Celsius

		FigS9.TIF

Figure S10:

	Height map optical microscope image of antimony telluride electrodeposited at 25 Celsius

		FigS10.TIF

Figure S11:

	Height map optical microscope image of antimony telluride electrodeposited at 120 Celsius

		FigS11.TIF

Figure S12:

	SEM image of Sb electrodeposited onto TiN working electrode from heating to 140 Celsius from o-dichlorobenzene
		
		FigS12.TIF

Figure S13:

	a) voltammogram at a TiN working electrode of antimony tetrachloride in o-dichlorobenzene before and after heating the solvent to 140 Celsius
	b) SEM image of Sb electrodeposited onto TiN from o-dichlorobenzene added after heating the solvent to 140 Celsius

		FigS13b.TIF

Figure S14:

	a) SEM image of Te precipitate collected after heating o-dichlorobenzene to 140 Celsius
	b) EDX spectrum of Te precipitate

		FigS14a.TIF